Physical Chemistry of Intercalated System

摘要: The driving force of development intercalation chemistry is significant improvement properties fabricated nanocomposites and design materials with new properties. Forming hybrid structures define important functional characteristics: improved mechanical strength (increase in modulus), enhanced stiffness, heat resistance (decrease thermal expansion coefficient), stability, other physical properties, water resistance, interesting barrier for gas separation, high flame fire electric electrochemical behavior, size chemical different from the simple additive In this chapter physico-chemical peculiarities natural synthetic layered various types are considered. Special attention paid to features polymerization monomers assembly polymers layers silicates as well formation by an direct their solutions or melts. practical value post-intercalation transformations “guest” molecules lattices “host” analysed. main data on structure inclusion (including those metal chalcogenides) summarized. problems future prospects such nanosystems outlined.