Molybdenum disulfide as the interfacial layer in the CuO–TiO 2 photocathode for photoelectrochemical cells
作者： Asad Mahmood , Fatih Tezcan , Gülfeza Kardaş
DOI: 10.1007/S10854-017-7124-Y
关键词: Chemical engineering 、 Photocurrent 、 Photocathode 、 Layer (electronics) 、 Photoelectrochemical cell 、 Molybdenum disulfide 、 Indium tin oxide 、 Dielectric spectroscopy 、 Nanotechnology 、 Materials science 、 Electrode
摘要: Photoelectrochemical cells guarantee the production of hydrogen as clean energy source to overcome crisis. In this study, we have explored impact MoS2 interfacial layer in CuO–TiO2 composite photocathode framework. The CuO was electrodeposited on indium tin oxide (ITO) coated glass substrates and subsequently treated at high temperature (550 °C for 2 h) develop CuO. fitting electrochemical impedance spectroscopy data revealed a decrease magnitude total (ǀZǀ) with between TiO2. magnitudes charge transfer resistance ITO/CuO, ITO/CuO/TiO2, ITO/CuO/MoS2/TiO2 electrodes were calculated 429,170, 18,490, 17,388 Ω cm−2, respectively. Likewise, photocurrent density increased addition interface up −0.73 mA cm2 which recorded −0.39 mA cm2. This study is critical future improvement potential materials enhanced response.
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Jingshan Luo, Ludmilla Steier, Min-Kyu Son, Marcel Schreier, Matthew T. Mayer, Michael Grätzel, Cu2O Nanowire Photocathodes for Efficient and Durable Solar Water Splitting Nano Letters. ,vol. 16, pp. 1848- 1857 ,(2016) , 10.1021/ACS.NANOLETT.5B04929
Matěj Velický, Mark A. Bissett, Colin R. Woods, Peter S. Toth, Thanasis Georgiou, Ian A. Kinloch, Kostya S. Novoselov, Robert A. W. Dryfe, Photoelectrochemistry of Pristine Mono- and Few-Layer MoS2. Nano Letters. ,vol. 16, pp. 2023- 2032 ,(2016) , 10.1021/ACS.NANOLETT.5B05317
Weiyong Yuan, Jia Yuan, Jiale Xie, Chang Ming Li, Polymer-Mediated Self-Assembly of TiO2@Cu2O Core–Shell Nanowire Array for Highly Efficient Photoelectrochemical Water Oxidation ACS Applied Materials & Interfaces. ,vol. 8, pp. 6082- 6092 ,(2016) , 10.1021/ACSAMI.6B00030
Zhebo Chen, Arnold J. Forman, Thomas F. Jaramillo, Bridging the Gap Between Bulk and Nanostructured Photoelectrodes: The Impact of Surface States on the Electrocatalytic and Photoelectrochemical Properties of MoS2 Journal of Physical Chemistry C. ,vol. 117, pp. 9713- 9722 ,(2013) , 10.1021/JP311375K
Mariano D. Susman, Yishay Feldman, Alexander Vaskevich, Israel Rubinstein, Chemical deposition of Cu(2)O nanocrystals with precise morphology control. ACS Nano. ,vol. 8, pp. 162- 174 ,(2014) , 10.1021/NN405891G
Damien Voiry, Raymond Fullon, Jieun Yang, Cecilia de Carvalho Castro e Silva, Rajesh Kappera, Ibrahim Bozkurt, Daniel Kaplan, Maureen J. Lagos, Philip E. Batson, Gautam Gupta, Aditya D. Mohite, Liang Dong, Dequan Er, Vivek B. Shenoy, Tewodros Asefa, Manish Chhowalla, The role of electronic coupling between substrate and 2D MoS2 nanosheets in electrocatalytic production of hydrogen. Nature Materials. ,vol. 15, pp. 1003- 1009 ,(2016) , 10.1038/NMAT4660
Arnab Dhara, Bibhutibhushan Show, Apurba Baral, Sumit Chabri, Arijit Sinha, Nil Ratan Bandyopadhyay, Nillohit Mukherjee, Core-shell CuO-ZnO p-n heterojunction with high specific surface area for enhanced photoelectrochemical (PEC) energy conversion Solar Energy. ,vol. 136, pp. 327- 332 ,(2016) , 10.1016/J.SOLENER.2016.07.022
S. Bhuvaneshwari, N. Gopalakrishnan, Hydrothermally synthesized Copper Oxide (CuO) superstructures for ammonia sensing Journal of Colloid and Interface Science. ,vol. 480, pp. 76- 84 ,(2016) , 10.1016/J.JCIS.2016.07.004
Masoud Salavati-Niasari, Faezeh Soofivand, Ali Sobhani-Nasab, Maryam Shakouri-Arani, Ali Yeganeh Faal, Samira Bagheri, Synthesis, characterization, and morphological control of ZnTiO3 nanoparticles through sol-gel processes and its photocatalyst application Advanced Powder Technology. ,vol. 27, pp. 2066- 2075 ,(2016) , 10.1016/J.APT.2016.07.018
Xiaohui Ren, Xiang Qi, Yongzhen Shen, Si Xiao, Guanghua Xu, Zhen Zhang, Zongyu Huang, Jianxin Zhong, 2D co-catalytic MoS2 nanosheets embedded with 1D TiO2 nanoparticles for enhancing photocatalytic activity Journal of Physics D. ,vol. 49, pp. 315304- ,(2016) , 10.1088/0022-3727/49/31/315304