作者: Avigdor Scherz , Roie Yerushalmi
DOI:
关键词: Stereochemistry 、 Mechanism (engineering) 、 Linker 、 Molecular spring 、 Ligand 、 Atom (order theory) 、 System property 、 Crystallography 、 Chemistry 、 Signal
摘要: Using a synthetic molecular spring device in system for dynamically controlling property, such as momentum, topography, and electronic behavior. System features (a) the having (i) at least one assembly each featuring chemical unit including one: (1) atom; (2) complexing group complexed to (3) axial ligand reversibly physicochemically paired with (4) substantially elastic linker; and, (ii) an activating mechanism directed atom-axial pair; (b) selected operatively coupled assembly, exhibiting property. Activating sends signal pairs, modifying thereby cycle of spring-type reversible transitions between contracted expanded linear conformational states linkers, causing controllable change