6,7-Bismethoxy-2,11-dihydroxytetraphenylene Derived Macrocycles: Synthesis, Structures, and Complexation with Fullerenes
作者： Chun-Lin Deng , Xiao-Dong Xiong , David T. W. Chik , Zongwei Cai , Xiao-Shui Peng
关键词: Chemistry 、 Diffraction 、 Fullerene 、 Toluene 、 Combinatorial chemistry 、 Solid-state 、 Block (telecommunications)
摘要: 6,7-Bismethoxy-2,11-dihydroxytetraphenylene (1), a novel building block of tetraphenylene-derived macrocycles, was synthesized via palladium-catalyzed cross-coupling reactions and characterized by X-ray diffraction. The relevant macrocyclic hosts derived from 1 have well-defined structures with fixed conformations both in solution solid state. They showed efficient unique properties toward complexation fullerenes C60 C70 toluene.
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