Laboratory model for the biosynthesis of vallesamine, apparicine, and related alkaloids

作者： A. Ian Scott , C.-L. Yeh , Dennis Greenslade

关键词: Apparicine 、 Organic chemistry 、 Biosynthesis 、 Alkaloid 、 Stereochemistry 、 Chemistry 、 Stemmadenine

摘要: The alkaloid vallesamine has been prepared by partial synthesis from stemmadenine using a modified Polonovsky reaction in sequence which provides biogenetic model for this class of alkaloid.