Synthesis and photoluminescence of multicolor tunable K3Gd(VO4)2:Eu3+ phosphors
作者： Yiru Wang , Xiaohua Liu , Yuntong Li , Lindan Jing
DOI: 10.1016/J.JALLCOM.2015.09.060
关键词: Doping 、 Gadolinium 、 Optoelectronics 、 Emission spectrum 、 Photoluminescence 、 Monoclinic crystal system 、 Analytical chemistry 、 Solid-state lighting 、 Materials science 、 Luminescence 、 Phosphor
摘要: Abstract Eu 3+ -activated novel potassium gadolinium double vanadates K 3 Gd(VO 4 ) 2 phosphors have been synthesized via solid-state reaction. The crystal phase, surface morphology and photoluminescence properties of the phosphor were investigated. X-ray diffraction results demonstrate that Gd 1− x (VO has monoclinic structure with space group p21/m(11). emission spectra suggest present an intense charge transfer band at 314 nm a strong red ( 5 D 0 → 7 F transition) 617 nm. optimum doping concentration ions in is around 50 mol% major mechanism for quenching exchange interaction. emitting light color can be tunable by varying excitation wavelength warm white achieved 337 nm. luminescence may potential applications as materials w-LEDs solid state lighting.
sci-hub.se 参考文章(40)
Martin M. Kimani, Joseph W. Kolis, Synthesis and luminescence studies of a novel white Dy:K3Y(VO4)2 and yellow emitting phosphor Dy,Bi:K3Y(VO4)2 with potential application in white light emitting diodes Journal of Luminescence. ,vol. 145, pp. 492- 497 ,(2014) , 10.1016/J.JLUMIN.2013.07.054
Wenrui CHANG, Dan WANG, Xingping PENG, Yuhua WANG, Lingzhi HU, Jing WANG, Photoluminescence properties of color-tunable KLaSiO4:Ce3+,Mn2+ phosphors Journal of Rare Earths. ,vol. 33, pp. 480- 485 ,(2015) , 10.1016/S1002-0721(14)60444-0
V. F. Kharsika, L. N. Komissarova, A. N. Kirichenko, E. N. Murav'ev, V. P. Orlovskii, A. P. Chernyaev, Luminescence Spectra of Eu3+-Activated Potassium Lanthanum and Potassium Gadolinium Phosphate Vanadates Inorganic Materials. ,vol. 37, pp. 963- 967 ,(2001) , 10.1023/A:1011666302396
Marcin Sobczyk, Damian Szymański, A study of optical properties of Sm3+ ions in α-Na3Y(VO4)2 single crystals Journal of Luminescence. ,vol. 142, pp. 96- 102 ,(2013) , 10.1016/J.JLUMIN.2013.03.062
Chung-Hao Chiang, Han-Yu Lin, Sheng-Yuan Chu, Cross relaxation of Sm3+ and energy transfer between Sm3+ and Eu3+ Ions in (Ca0.97Sr0.03)3(VO4)2 phosphor host Journal of the American Ceramic Society. ,vol. 97, pp. 3737- 3739 ,(2014) , 10.1111/JACE.13335
W.L. Zhu, Y.Q. Ma, C. Zhai, K. Yang, X. Zhang, D.D. Wu, G. Li, G.H. Zheng, Photoluminescence properties of Sr3(VO4)2, Sr2Y2/3−yEuy(VO4)2 and Sr2Y2/3−zSmz(VO4)2 Optical Materials. ,vol. 33, pp. 1162- 1166 ,(2011) , 10.1016/J.OPTMAT.2011.01.019
Xinguo Zhang, Liya Zhou, Menglian Gong, High-brightness Eu3+-doped Ca3(PO4)2 red phosphor for NUV light-emitting diodes application Optical Materials. ,vol. 35, pp. 993- 997 ,(2013) , 10.1016/J.OPTMAT.2012.12.023
Anant A. Setlur, Emil V. Radkov, Claire S. Henderson, Jae-Hyuk Her, Alok M. Srivastava, Nagaveni Karkada, M. Satya Kishore, N. Prasanth Kumar, Danny Aesram, Anirudha Deshpande, Boris Kolodin, Ljudmil S. Grigorov, Uwe Happek, Energy-Efficient, High-Color-Rendering LED Lamps Using Oxyfluoride and Fluoride Phosphors Chemistry of Materials. ,vol. 22, pp. 4076- 4082 ,(2010) , 10.1021/CM100960G
Mingming Shi, Dongyun Zhang, Chengkang Chang, None, Tunable emission and concentration quenching of Tb3+ in magnesium phosphate lithium Journal of Alloys and Compounds. ,vol. 627, pp. 25- 30 ,(2015) , 10.1016/J.JALLCOM.2014.11.178
Zhenhe Xu, Xiaojiao Kang, Chunxia Li, Zhiyao Hou, Cuimiao Zhang, Dongmei Yang, Guogang Li, Jun Lin, Ln3+ (Ln = Eu, Dy, Sm, and Er) Ion-Doped YVO4 Nano/Microcrystals with Multiform Morphologies: Hydrothermal Synthesis, Growing Mechanism, and Luminescent Properties Inorganic Chemistry. ,vol. 49, pp. 6706- 6715 ,(2010) , 10.1021/IC100953M