Alkylcarbene complex of tantalum by intramolecular .alpha.-hydrogen abstraction

作者: Richard R. Schrock

DOI: 10.1021/JA00828A061

关键词: Computational chemistryTantalumPhysical organic chemistryChemical reaction kineticsHydrogen atom abstractionChemistryChemical preparationIntramolecular forceAlpha (ethology)Inorganic chemistryColloid and Surface ChemistryBiochemistryGeneral chemistryCatalysis

摘要: … is a doublet due to coupling to the single a-hydrogen (J = 90 Hz). Other resonances … formed by abstraction of a neopentyl -hydrogen by a second neopentyl group in a statistical manner …

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