XPS analysis of palladium oxide layers and particles
作者： E.H. Voogt , A.J.M. Mens , O.L.J. Gijzeman , J.W. Geus
DOI: 10.1016/0039-6028(96)01028-X
关键词: Sintering 、 Particle size 、 Monolayer 、 Oxide 、 X-ray photoelectron spectroscopy 、 Chemistry 、 FOIL method 、 Metal 、 Analytical chemistry 、 Palladium
摘要: Abstract The thermal reduction of both oxidised palladium foil and SiO 2 Si (100) supported oxide particles, ranging in size fro 3.5 to 13 nm, was investigated with XPS. Equations were derived for the XPS intensities, measured at normal emission angles, particles which consisted a metallic core an oxidic skin. By applying these equations on spectra after each step, particle calculated. Measurements showed that layer thickness decreases linearly time up last monolayer oxide. rate surface is about eight times lower than bulk growth appeared be proportional area. smallest comparable foil. larger behave identical
harvard.edu
elsevier.com
sci-hub.se 参考文章(21)
P.J. Schmitz, K. Otto, J.E. de Vries, An X-ray photoelectron spectroscopy investigation of palladium in automotive catalysts Applied Catalysis A: General. ,vol. 92, pp. 59- 72 ,(1992) , 10.1016/0926-860X(92)80279-L
K. Otto, C.P. Hubbard, W.H. Weber, G.W. Graham, Raman spectroscopy of palladium oxide on γ-alumina applicable to automotive catalysts Applied Catalysis B: Environmental. ,vol. 1, pp. 317- 327 ,(1992) , 10.1016/0926-3373(92)80056-6
JWM Jacobs, D Schryvers, A high-resolution electron microscopy study of photodeposited Pd particles on TiO2 and their oxidation in air Journal of Catalysis. ,vol. 103, pp. 436- 449 ,(1987) , 10.1016/0021-9517(87)90135-7
James J. Chen, Eli Ruckenstein, Role of interfacial phenomena in the behavior of alumina-supported palladium crystallites in oxygen The Journal of Physical Chemistry. ,vol. 85, pp. 1606- 1612 ,(1981) , 10.1021/J150611A029
A. Ogata, A. Obuchi, K. Mizuno, A. Ohi, H. Ohuchi, Active Sites and Redox Properties of Supported Palladium Catalysts for Nitric Oxide Direct Decomposition Journal of Catalysis. ,vol. 144, pp. 452- 459 ,(1993) , 10.1006/JCAT.1993.1345
Robert F Hicks, Haihua Qi, Michael L Young, Raymond G Lee, Effect of catalyst structure on methane oxidation over palladium on alumina Journal of Catalysis. ,vol. 122, pp. 295- 306 ,(1990) , 10.1016/0021-9517(90)90283-P
Theo H Fleisch, Robert F Hicks, Alexis T Bell, An XPS study of metal-support interactions on Pd/SiO2 and Pd/La2O3 Journal of Catalysis. ,vol. 87, pp. 398- 413 ,(1984) , 10.1016/0021-9517(84)90200-8
T.E. Hoost, K. Otto, Temperature-programmed study of the oxidation of palladium/alumina catalysts and their lanthanum modification Applied Catalysis A: General. ,vol. 92, pp. 39- 58 ,(1992) , 10.1016/0926-860X(92)80278-K
E Ruckenstein, J.J Chen, Wetting phenomena during alternating heating in O2 and H2 of supported metal crystallites Journal of Colloid and Interface Science. ,vol. 86, pp. 1- 11 ,(1982) , 10.1016/0021-9797(82)90034-0
K. Otto, L.P. Haack, J.E. deVries, Identification of two types of oxidized palladium on γ-alumina by X-ray photoelectron spectroscopy Applied Catalysis B-environmental. ,vol. 1, pp. 1- 12 ,(1992) , 10.1016/0926-3373(92)80003-I