A crosslinked fullerene matrix doped with an ionic fullerene as a cathodic buffer layer toward high-performance and thermally stable polymer and organic metallohalide perovskite solar cells
作者： Yi-Hsiang Chao , Yi-You Huang , Jen-Yun Chang , Shih-Hao Peng , Wei-Yi Tu
DOI: 10.1039/C5TA05057J
关键词: Thermal stability 、 Dopant 、 Materials science 、 Heterojunction 、 Perovskite (structure) 、 Organic chemistry 、 Polymer solar cell 、 Layer (electronics) 、 Chemical engineering 、 Ionic bonding 、 Fullerene
摘要: In this study, we developed a new cathodic buffer layer consisting of cross-linked [6,6]-phenyl-C61-butyric styryl dendron ester (C-PCBSD) matrix and an ionic FPI dopant. The incorporation can improve the electron mobility via anion induced charge transfer (AIET) mechanism, while maintaining solvent-resistant properties crosslinked layer. ZnO combined with C-PCBSD/FPI effectively universally performance bulk-heterojunction polymer solar cells (BHJPSCs), planar heterojunction (PHJPSCs), organic metallohalide perovskite (OMPSCs). Furthermore, insertion thermal stability device by preventing residual moisture in from diffusing into CH3NH3PbI3 OMPSCs.
rsc.org
nctu.edu.tw
iccas.ac.cn参考文章(43)
M. M. Lee, J. Teuscher, T. Miyasaka, T. N. Murakami, H. J. Snaith, Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites Science. ,vol. 338, pp. 643- 647 ,(2012) , 10.1126/SCIENCE.1228604
Qifan Xue, Zhicheng Hu, Jiang Liu, Jiahui Lin, Chen Sun, Ziming Chen, Chunhui Duan, Jing Wang, Cheng Liao, Woon Ming Lau, Fei Huang, Hin-Lap Yip, Yong Cao, Highly efficient fullerene/perovskite planar heterojunction solar cells via cathode modification with an amino-functionalized polymer interlayer Journal of Materials Chemistry. ,vol. 2, pp. 19598- 19603 ,(2014) , 10.1039/C4TA05352D
Jun-Yuan Jeng, Yi-Fang Chiang, Mu-Huan Lee, Shin-Rung Peng, Tzung-Fang Guo, Peter Chen, Ten-Chin Wen, CH3NH3PbI3Perovskite/Fullerene Planar-Heterojunction Hybrid Solar Cells Advanced Materials. ,vol. 25, pp. 3727- 3732 ,(2013) , 10.1002/ADMA.201301327
Chang-Zhi Li, Chih-Yu Chang, Yue Zang, Huan-Xin Ju, Chu-Chen Chueh, Po-Wei Liang, Namchul Cho, David S. Ginger, Alex K.-Y. Jen, Suppressed Charge Recombination in Inverted Organic Photovoltaics via Enhanced Charge Extraction by Using a Conductive Fullerene Electron Transport Layer Advanced Materials. ,vol. 26, pp. 6262- 6267 ,(2014) , 10.1002/ADMA.201402276
Chang-Zhi Li, Chu-Chen Chueh, Hin-Lap Yip, Feizhi Ding, Xiaosong Li, Alex K.-Y. Jen, Solution-Processible Highly Conducting Fullerenes Advanced Materials. ,vol. 25, pp. 2457- 2461 ,(2013) , 10.1002/ADMA.201204543
Mathis-Andreas Muth, William Mitchell, Steven Tierney, Thomas A Lada, Xiang Xue, Henning Richter, Miguel Carrasco-Orozco, Mukundan Thelakkat, Influence of charge carrier mobility and morphology on solar cell parameters in devices of mono- and bis-fullerene adducts. Nanotechnology. ,vol. 24, pp. 484001- 484001 ,(2013) , 10.1088/0957-4484/24/48/484001
Chao-Hsiang Hsieh, Yen-Ju Cheng, Pei-Jung Li, Chiu-Hsiang Chen, Martin Dubosc, Ru-Meng Liang, Chain-Shu Hsu, Highly Efficient and Stable Inverted Polymer Solar Cells Integrated with a Cross-Linked Fullerene Material as an Interlayer Journal of the American Chemical Society. ,vol. 132, pp. 4887- 4893 ,(2010) , 10.1021/JA100236B
Chang-Wen Chen, Hao-Wei Kang, Sheng-Yi Hsiao, Po-Fan Yang, Kai-Ming Chiang, Hao-Wu Lin, Efficient and Uniform Planar‐Type Perovskite Solar Cells by Simple Sequential Vacuum Deposition Advanced Materials. ,vol. 26, pp. 6647- 6652 ,(2014) , 10.1002/ADMA.201402461
Dianyi Liu, Mahesh K. Gangishetty, Timothy L. Kelly, Effect of CH3NH3PbI3 thickness on device efficiency in planar heterojunction perovskite solar cells Journal of Materials Chemistry. ,vol. 2, pp. 19873- 19881 ,(2014) , 10.1039/C4TA02637C
Jangwon Seo, Sangman Park, Young Chan Kim, Nam Joong Jeon, Jun Hong Noh, Sung Cheol Yoon, Sang Il Seok, Benefits of very thin PCBM and LiF layers for solution-processed p–i–n perovskite solar cells Energy and Environmental Science. ,vol. 7, pp. 2642- 2646 ,(2014) , 10.1039/C4EE01216J