Relationship between structural attributes and observed electrogenerated chemiluminescence (ECL) activity of tertiary amines as potential analytes for the tris(2,2-bipyridine)ruthenium(II) ECL reaction. A review

作者: Andrew W. Knight , Gillian M. Greenway

DOI: 10.1039/AN996210101R

关键词: ChemiluminescenceAmine gas treatingOrganic chemistry2,2'-BipyridineTrisRutheniumReactivity (chemistry)Combinatorial chemistryReaction mechanismTertiary amineChemistry

摘要: The relationship between the structural attributes of various amine compounds and their observed electrogenerated chemiluminescence (ECL) activity with tris(2,2-bipyridine)ruthenium(II) ECL reaction was examined, a view to determination these compounds. This carried out by first examining mechanism then predicting certain classes considering stability intermediates, drawing general conclusions comparing observations obtained authors other workers. molecular geometry alternative anodic reactivity effect on are discussed results for range local anaesthetics presented.

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