Post‐Synthesis Treatment gives Highly Stable Siliceous Zeolites through the Isomorphous Substitution of Silicon for Germanium in Germanosilicates
作者： Hao Xu , Jin-gang Jiang , Boting Yang , Lin Zhang , Mingyuan He
关键词: Silicon 、 Isomorphous substitution 、 Chemistry 、 Stabilization methods 、 Inorganic chemistry 、 Germanium 、 Acid treatment 、 Hydrothermal circulation 、 Post synthesis
摘要: Germanosilicates, an important family of zeolites with increasing number members and attractive porosities, but containing a large quantity unstable Ge atoms in the framework, meet great obstacles terms limited thermal hydrothermal stability when it comes to practical use. A facile stabilization method thus has been developed substitute isomorphously for Si atoms, giving rise ultrastable siliceous analogues pristine germanosilicates.
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