Pincer ligands based on α-amino acids: III. New ligands based on 4-substituted phenols and their copper complexes. Enantioselective recognition of tyrosine

作者： N. E. Borisova , V. A. Knizhnikov , T. G. Gulevich , M. Yu. Seliverstov , E. A. Borisov

关键词: Enantioselective synthesis 、 Enantiomer 、 Tyrosine 、 Chemistry 、 Amino acid 、 Stereochemistry 、 Schiff base 、 Copper 、 Aqueous solution 、 Pincer movement 、 Organic chemistry

摘要: Reactions of L-methionine, L-serine, and L-valine with 5-substituted-2-hydroxybenzene-1,3-dicarbaldehydes gave a series chiral Schiff base pincer ligands which were reduced to the corresponding diamines. The new reacted copper(II) chloride form dinuclear copper complexes found be capable recognizing tyrosine enantiomers in aqueous solution. structure was determined on basis their spectral parameters.

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Pincer ligands based on α-amino acids: III. New ligands based on 4-substituted phenols and their copper complexes. Enantioselective recognition of tyrosine

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Pincer ligands based on α-amino acids: III. New ligands based on 4-substituted phenols and their copper complexes. Enantioselective recognition of tyrosine

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