Experimental investigation of interfacial tension in two-phase system involving methane and water

作者: AA Yahaya

DOI:

关键词: BrineMaterials scienceApparent viscosityViscosityConductivityAqueous solutionShear rateChemical engineeringPEG ratioSurface tension

摘要: The understanding of the physical properties reservoir fluids such as viscous and interfacial forces is critical in many oil gas, petrochemical, other related industries. In gas industry, production, transportation processing hydrocarbon involve dealing with multiphase system. Viscosity tension (IFT) are among fluid that affect behaviour. These have significant effects on flow characteristics, thus their importance production aspects from to surface facilities. Hence accurate determination these plays a vital role predicting managing associated problems faced by industry hydrates, scale corrosion. Surfactants added along line, prevent hydrate formation, depressing formation temperature, transport it slurry when formed avoid pipe blockages. While research has been conducted conditions, but Pipeline system, presence salt polymer-surfactants which tend alter IFT behaviour not well studied. This study investigates methane/water experimentally (NaCl) (PEG 8000-SDS) at operating conditions suitable for upstream midstream application. Also, experimental investigation pH, resistivity, conductivity, viscosity density liquid phase (brine + polymer-surfactant) was characterises phase. The results show electrical resistivity conductivity depend significantly ionic concentration NaCl presents. Resistivity decreases increasing 0.22 Ω-m 2.9 wt% 0.075 10.7wt% NaCl, shows possibility corroding case pipeline measured an increase 4.55 13.33 S/m 10.7 respectively. This affirmed strength could cause scaling corrosion High system also signifies potentially harmful accumulation solids cooling towers. Conductivity investigated function temperature. all studied, temperature (298.15, 303.15, 308.15 313.15 K) led corresponding average 0.74 values ionisation. Results obtained affects pH solution. value observed 6.5 ≈ 7.0 8.2 40 PEG 8000 same 6.9. Knowing aqueous solutions, accurately determine solution determines much SDS were presented 298.15 – K. shear stress 10 found increased 0.14 Pa 28.1 s-1 7.6 340.5 indicating Newtonian apparent curve obtained, 3.7 cP 58.1 8000. However, each concentration, be decreasing rate. Results two-phase involving methane water pressure, salinity, surfactant/polymer. Both pressure working CH4-H2O. Presences 2.9, 5.6, resulted rise 1.46, 2.57, 3.51 4.24 mN.m-1 respectively, IFT. due pipeline. Further, active reduces IFT, micelle-like 30 more effect addition 0.5 SDS. Therefore, percentage good combination prevention Some evaluated against independent data gathered open sources validate method methane-water interface 8000, here reported first time.

参考文章(60)
F.K Hansen, G Rødsrud, Surface tension by pendant drop Journal of Colloid and Interface Science. ,vol. 141, pp. 1- 9 ,(1991) , 10.1016/0021-9797(91)90296-K
Joseph D. Berry, Michael J. Neeson, Raymond R. Dagastine, Derek Y.C. Chan, Rico F. Tabor, Measurement of surface and interfacial tension using pendant drop tensiometry joint international conference on information sciences. ,vol. 454, pp. 226- 237 ,(2015) , 10.1016/J.JCIS.2015.05.012
D. Möbius, Reinhard Miller, Drops and bubbles in interfacial research Elsevier. ,(1998)
Michael Kappl, Karlheinz Graf, Hans-Jürgen Butt, Physics and Chemistry of Interfaces ,(2003)
Mostafa Lashkarbolooki, Masoud Riazi, Shahab Ayatollahi, Ali Zeinolabedini Hezave, Synergy effects of ions, resin, and asphaltene on interfacial tension of acidic crude oil and low–high salinity brines Fuel. ,vol. 165, pp. 75- 85 ,(2016) , 10.1016/J.FUEL.2015.10.030
M. Dominik, K. W. Cassel, Analysis of Initial Bubble Acceleration Using the Level-Set Method The Journal of Computational Multiphase Flows. ,vol. 7, pp. 129- 142 ,(2015) , 10.1260/1757-482X.7.3.129
Pierre Chiquet, Jean-Luc Daridon, Daniel Broseta, Sylvain Thibeau, CO2/water interfacial tensions under pressure and temperature conditions of CO2 geological storage Energy Conversion and Management. ,vol. 48, pp. 736- 744 ,(2007) , 10.1016/J.ENCONMAN.2006.09.011