Honeycomb supports with high thermal conductivity for gas/solid chemical processes

作者: Gianpiero Groppi , Enrico Tronconi

DOI: 10.1016/J.CATTOD.2005.06.041

关键词: Heat transfer coefficientThermalMaterials scienceComposite materialHoneycombMonolithExothermic reactionThermal conductionThermal conductivityThermal resistance

摘要: Abstract The scope of this review article is to address the use novel monolithic catalysts with high thermal conductivity in externally cooled tubular reactors for gas/solid exothermic chemical processes place conventional packed beds catalyst pellets. After discussing analysis and implications heat conduction honeycomb monolith structures, we herein simulation studies experimental investigations showing that near-isothermal reactor operation can be achieved even under very loads by adopting specific materials designs supports associated effective radial conductivities. For such monoliths, limiting resistance located at interface between inner tube wall (“gap resistance”). Recent measurements “gap” transfer coefficient point large values (>400 W/(m 2  K)), which are controlled both tube–monolith clearance actual operating conditions process gas.

参考文章(16)
Andrzej Cybulski, Jacob A Moulijn, Structured Catalysts and Reactors CRC Press. ,(2005) , 10.1201/9781420028003
Gianpiero Groppi, Enrico Tronconi, Design of novel monolith catalyst supports for gas/solid reactions with heat exchange Chemical Engineering Science. ,vol. 55, pp. 2161- 2171 ,(2000) , 10.1016/S0009-2509(99)00440-6
Enrico Tronconi, Gianpiero Groppi, Thorsten Boger, Achim Heibel, Monolithic catalysts with ‘high conductivity’ honeycomb supports for gas/solid exothermic reactions: characterization of the heat-transfer properties Chemical Engineering Science. ,vol. 59, pp. 4941- 4949 ,(2004) , 10.1016/J.CES.2004.07.018
M. Flytzani-Stephanopoulos, G.E. Voecks, T. Charng, Modelling of heat transfer in non-adiabatic monolith reactors and experimental comparisons of metal monoliths with packed beds Chemical Engineering Science. ,vol. 41, pp. 1203- 1212 ,(1986) , 10.1016/0009-2509(86)87093-2
A. Parmaliana, C. Crisafulli, R. Maggiore, J. C. J. Bart, N. Giordano, Catalytic activity of honeycomb catalysts, I. The benzene-cyclohexane (de)hydrogenation reaction Reaction Kinetics and Catalysis Letters. ,vol. 18, pp. 295- 299 ,(1981) , 10.1007/BF02065610
Thorsten Boger, Achim K. Heibel, Heat transfer in conductive monolith structures Chemical Engineering Science. ,vol. 60, pp. 1823- 1835 ,(2005) , 10.1016/J.CES.2004.11.031
Ronald M. Heck, Suresh Gulati, Robert J. Farrauto, The application of monoliths for gas phase catalytic reactions Chemical Engineering Journal. ,vol. 82, pp. 149- 156 ,(2001) , 10.1016/S1385-8947(00)00365-X