Lixcuymo6s8 - a Pseudoternary Intercalation Compound

作者: W R McKinnon , J R Dahn , C C H Jui

DOI: 10.1088/0022-3719/18/23/009

关键词: CrystallographyIntercalation (chemistry)DiffractionTernary phase diagramTernary plotElectrochemical cellDelta-v (physics)Materials science

摘要: … M ~ 6 S 8 by reacting Cu, S and Li2S powder and MO foil at 950C. Although the amounts of starting materials were chosen to give Liz,7Cu,Mo6S8, some of the Li reacted with the quartz …

参考文章(20)
W. R. McKinnon, J. R. Dahn, Structure and electrochemistry of LixMo6S8. Physical Review B. ,vol. 31, pp. 3084- 3087 ,(1985) , 10.1103/PHYSREVB.31.3084
J R Dahn, W R McKinnon, Lithium intercalation in 2H-LixTaS2 Journal of Physics C: Solid State Physics. ,vol. 17, pp. 4231- 4243 ,(1984) , 10.1088/0022-3719/17/24/006
W.R. McKinnon, J.R. Dahn, Salting-out in intercalation compounds: Removing copper from Cu3Mo6S8 by intercalating lithium Solid State Communications. ,vol. 52, pp. 245- 248 ,(1984) , 10.1016/0038-1098(84)90817-2
Ryoichi Kikuchi, Ternary phase diagram calculations—I General theory Acta Metallurgica. ,vol. 25, pp. 195- 205 ,(1977) , 10.1016/0001-6160(77)90123-7
M. Tovar, L.E. DeLong, D.C. Johnston, M.B. Maple, Superconductivity and crystal structure of ternary CuxMo3S4 compounds with 0 ≤ x ≤ 1 prepared by anodic oxidation of Cu1.0Mo3S4 Solid State Communications. ,vol. 30, pp. 551- 557 ,(1979) , 10.1016/0038-1098(79)91135-9
R. Schöllhorn, M. Kümpers, A. Lerf, E. Umlauf, W. Schmidt, Structure and superconductivity of ternary chalcogenides CuxMo6S8 prepared by topotactic electrode reactions Materials Research Bulletin. ,vol. 14, pp. 1039- 1047 ,(1979) , 10.1016/0025-5408(79)90069-2
Ryoichi Kikuchi, Didier de Fontaine, Masanori Murakami, Tsutomu Nakamura, Ternary phase diagram calculations—II Examples of clustering and ordering systems Acta Metallurgica. ,vol. 25, pp. 207- 219 ,(1977) , 10.1016/0001-6160(77)90124-9
David C. Johnston, Ambient temperature phase relations in the system ifNa13(H2O)yTaS2 (0<-y<-2) Materials Research Bulletin. ,vol. 17, pp. 13- 23 ,(1982) , 10.1016/0025-5408(82)90177-5
S.K. Hark, B.R. York, S.D. Mahanti, S.A. Solin, Tuneable sandwich thickness in potassium-ammonia graphite intercalation compounds Solid State Communications. ,vol. 50, pp. 595- 599 ,(1984) , 10.1016/0038-1098(84)90136-4