Experimental determination of the phase behavior of binary mixtures of methane + benzene

作者: M.P.W.M. Rijkers , M. Malais , C.J. Peters , J. de Swaan Arons

DOI: 10.1016/0378-3812(92)85112-L

关键词: Phase (matter)Analytical chemistryFluid phaseChemistryBinary numberAutoclaveMethaneBenzeneOrganic chemistry

摘要: Rijkers M.P.W.M., Malais M., Peters C.J. and de Swaan Arons, J., 1992. Experimental determination of the phase behavior binary mixtures methane + benzene. Part I. Vapor liquid, solid benzene vapor liquid equilibria. Fluid Phase Equilibria, 77: 327–342. This paper reports experimental results various types two-phase boundaries in The measurements were performed temperature region from about 260 to 350 K pressures up 80 MPa applied, using windowed autoclave equipment. From obtained course three-phase equilibrium was derived.

参考文章(14)
M Glaser, C.J Peters, H.J Van Der Kool, R.N Lichtenthaler, Phase equilibria of (methane + n-hexadecane) and (p, Vm, T) of n-hexadecane The Journal of Chemical Thermodynamics. ,vol. 17, pp. 803- 815 ,(1985) , 10.1016/0021-9614(85)90072-2
M. Elbishlawi, J. R. Spencer, Equilibrium Relations of Two Methane-Aromatic Binary Systems at 150° F. Industrial & Engineering Chemistry. ,vol. 43, pp. 1811- 1815 ,(1951) , 10.1021/IE50500A036
J. M. Prausnitz, R. N. Keeler, Application of the Kihara potential to high pressure phase equilibria Aiche Journal. ,vol. 7, pp. 399- 405 ,(1961) , 10.1002/AIC.690070311
Hedzer Johannes van der Kooi, Metingen en berekeningen aan het systeem methaan-n-eicosaan Delft University Press. ,(1981)
G.J. van Rossum, C.A.M.G. Cramers, Trends in the analysis of natural gas by capillary gas chromatography Elsevier. ,(1986)
M.P.W.M. Rijkers, C.J. Peters, J. de Swaan Arons, Measurements on the phase behavior of binary mixtures for modeling the condensation behavior of natural gas Fluid Phase Equilibria. ,vol. 85, pp. 335- 345 ,(1993) , 10.1016/0378-3812(93)80023-G
R.P.W.M. Rijkers, Retrograde condensation of lean natural gas Delftse Universitaire Pers. ,(1991)
G. P. Kuebler, C. McKinley, Solubility of Solid Benzene, Toluene, n-Hexane, and n-Heptane in Liquid Methane Adv. Cryog. Eng.; (United States). ,vol. 19, pp. 320- 326 ,(1995) , 10.1007/978-1-4613-9847-9_39