Pyrolysis of petroleum fractions

作者: Maria Luisa A. Gonçalves , Deusa Angélica da Mota Pinto , Ana Maria R. F. Teixeira , M. A. G. Teixeira

DOI: 10.1007/S10973-006-8176-Z

关键词: ThermogravimetryKinetic energyMineralogyPetroleumAnalytical chemistryChemistryPyrolysisDistillationThermal analysisRaw materialRefinery

摘要: Dynamic kinetic analyses were performed on different Brazilian petroleum fractions by thermogravimetry. The data treated a multiple heating rate methodology. apparent activation energies for the light and middle within range of 62–74 kJ mol−1 heavy distillation residues 80–100 at lower conversions 100–240 higher conversions. study can be criterion tells apart main phenomena involved in thermal behavior refinery feedstock.

参考文章(16)
Sergey Vyazovkin, Computational aspects of kinetic analysis. Thermochimica Acta. ,vol. 355, pp. 155- 163 ,(2000) , 10.1016/S0040-6031(00)00445-7
Aprameya Ambalae, Nader Mahinpey, Norman Freitag, Thermogravimetric Studies on Pyrolysis and Combustion Behavior of a Heavy Oil and Its Asphaltenes Energy & Fuels. ,vol. 20, pp. 560- 565 ,(2006) , 10.1021/EF0502812
Maria Luisa A. Gonçalves, Deusa A. Pinto da Mota, Ana Maria R. F. Teixeira, M. A. G. Teixeira, Thermogravimetric investigation on prediction of thermal behavior of petroleum distillation residues Journal of Thermal Analysis and Calorimetry. ,vol. 80, pp. 81- 86 ,(2005) , 10.1007/S10973-005-0617-6
Mustafa Versan Kök, Özgen Karacan, Reha Pamir, Kinetic analysis of oxidation behavior of crude oil SARA constituents Energy & Fuels. ,vol. 12, pp. 580- 588 ,(1998) , 10.1021/EF970173I
Mustafa Verşan Kök, Ozgen Karacan, Pyrolysis Analysis and Kinetics of Crude Oils Journal of Thermal Analysis and Calorimetry. ,vol. 52, pp. 781- 788 ,(1998) , 10.1023/A:1010114624345
Mustafa Versan Kök, M.Reha Pamir, Pyrolysis and combustion studies of fossil fuels by thermal analysis methods Journal of Analytical and Applied Pyrolysis. ,vol. 35, pp. 145- 156 ,(1995) , 10.1016/0165-2370(95)00912-0
Takeo Ozawa, A New Method of Analyzing Thermogravimetric Data Bulletin of the Chemical Society of Japan. ,vol. 38, pp. 1881- 1886 ,(1965) , 10.1246/BCSJ.38.1881
M. Ranjbar, G. Pusch, Pyrolysis and combustion kinetics of crude oils, asphaltenes and resins in relation to thermal recovery processes Journal of Analytical and Applied Pyrolysis. ,vol. 20, pp. 185- 196 ,(1991) , 10.1016/0165-2370(91)80072-G
Ozgen Karacan, Mustafa Versan Kok, Pyrolysis Analysis of Crude Oils and Their Fractions Energy & Fuels. ,vol. 11, pp. 385- 391 ,(1997) , 10.1021/EF960162+
J.A. Conesa, A. Marcilla, J.A. Caballero, R. Font, Comments on the validity and utility of the different methods for kinetic analysis of thermogravimetric data Journal of Analytical and Applied Pyrolysis. ,vol. 58, pp. 617- 633 ,(2001) , 10.1016/S0165-2370(00)00130-3