Self-assembling Ni(OH)2/α-Fe2O3 composites for pseudocapacitors with excellent electrochemical performance.

作者: Zijiong Li , Weiyang Zhang , Yuling Su , Zhikun Li , Jonathan Groeper

DOI: 10.1088/1361-6528/28/4/045603

关键词: NanosheetComposite materialElectrochemistryAqueous electrolyteMaterials scienceCurrent densityPseudocapacitorCapacitanceSelf assemblingElectrode material

摘要: Novel two-dimensional (2D) nanostructured Ni(OH)2 nanosheet/α-Fe2O3 nanoplate composites (NFCs) were successfully synthesized by a simple two-step solvothermal method where the proportion of α-Fe2O3 nanoplates was found to be controllable. These achieved excellent performance in aqueous electrolyte due synergistic effect between nanosheets and nanoplates, such as high specific capacitance long-term cycle stability. The obtained NFC8 possessed maximum mass 1745.33F g−1 at current density 2 A g−1, with 84.28% retention after 3000 cycles galvanostatic charge/discharge 20 g−1. above results show that these novel 2D Ni(OH)2/α-Fe2O3 are promising electrode materials for pseudocapacitors.

参考文章(46)
Yi Cao, Baoping Lin, Ying Sun, Hong Yang, Xueqin Zhang, Sr-doped Lanthanum Nickelate Nanofibers for High Energy Density Supercapacitors Electrochimica Acta. ,vol. 174, pp. 41- 50 ,(2015) , 10.1016/J.ELECTACTA.2015.05.131
Jinglin Zhang, Lei Shi, Huidi Liu, Zewei Deng, Langhuan Huang, Wenjie Mai, Shaozao Tan, Xiang Cai, Utilizing polyaniline to dominate the crystal phase of Ni(OH)2 and its effect on the electrochemical property of polyaniline/Ni(OH)2 composite Journal of Alloys and Compounds. ,vol. 651, pp. 126- 134 ,(2015) , 10.1016/J.JALLCOM.2015.08.090
Xiaoqian Meng, Junwu Zhu, Huiping Bi, Yongsheng Fu, Qiaofeng Han, Xin Wang, Three-dimensional nickel hydroxide/graphene composite hydrogels and their transformation to NiO/graphene composites for energy storage Journal of Materials Chemistry. ,vol. 3, pp. 21682- 21689 ,(2015) , 10.1039/C5TA05008A
Hang Zhang, Qiuming Gao, Kai Yang, Yanli Tan, Weiqian Tian, Lihua Zhu, Zeyu Li, Chunxiao Yang, Solvothermally induced α-Fe2O3/graphene nanocomposites with ultrahigh capacitance and excellent rate capability for supercapacitors Journal of Materials Chemistry. ,vol. 3, pp. 22005- 22011 ,(2015) , 10.1039/C5TA06668A
Yukun Wang, Lichun Yang, Renzong Hu, Wei Sun, Jiangwen Liu, Liuzhang Ouyang, Bin Yuan, Haihui Wang, Min Zhu, A stable and high-capacity anode for lithium-ion battery: Fe2O3 wrapped by few layered graphene Journal of Power Sources. ,vol. 288, pp. 314- 319 ,(2015) , 10.1016/J.JPOWSOUR.2015.04.076
Grzegorz Lota, Krzysztof Fic, Elzbieta Frackowiak, Carbon nanotubes and their composites in electrochemical applications Energy and Environmental Science. ,vol. 4, pp. 1592- 1605 ,(2011) , 10.1039/C0EE00470G
Jun Wu, Chunhui Chen, Yong Hao, Chunlei Wang, Enhanced electrochemical performance of nanosheet ZnO/reduced graphene oxide composites as anode for lithium-ion batteries Colloids and Surfaces A: Physicochemical and Engineering Aspects. ,vol. 468, pp. 17- 21 ,(2015) , 10.1016/J.COLSURFA.2014.12.009
Chunxiao Yang, Qiuming Gao, Weiqian Tian, Yanli Tan, Tao Zhang, Kai Yang, Lihua Zhu, Superlow load of nanosized MnO on a porous carbon matrix from wood fibre with superior lithium ion storage performance Journal of Materials Chemistry. ,vol. 2, pp. 19975- 19982 ,(2014) , 10.1039/C4TA04471A
Li Wang, Xiaohong Wang, Xianping Xiao, Fugang Xu, Yujing Sun, Zhuang Li, Reduced graphene oxide/nickel cobaltite nanoflake composites for high specific capacitance supercapacitors Electrochimica Acta. ,vol. 111, pp. 937- 945 ,(2013) , 10.1016/J.ELECTACTA.2013.08.094