The unusual role of Li6PS5Br in all-solid-state CuS/Li6PS5Br/In–Li batteries

作者: Maohua Chen , Rayavarapu Prasada Rao , Stefan Adams

DOI: 10.1016/J.SSI.2014.05.004

关键词: Fast ion conductorReaction mechanismInorganic chemistryChemistryDissociation (chemistry)CathodeArgyroditeIonElectrolyteIonic conductivity

摘要: … Br) are promising solid electrolytes for rechargeable all-solid-state lithium batteries. Here we realized all-solid-state lithium batteries combining Li 6 PS 5 Br with CuS as the cathode. An …

参考文章(17)
W. F. Kuhs, R. Nitsche, K. Scheunemann, The crystal structure of Cu6PS5Br, a new superionic conductor Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. ,vol. 34, pp. 64- 70 ,(1978) , 10.1107/S0567740878002307
Maohua Chen, Rayavarapu Prasada Rao, Stefan Adams, High capacity all-solid-state Cu–Li2S/Li6PS5Br/In batteries Solid State Ionics. ,vol. 262, pp. 183- 187 ,(2014) , 10.1016/J.SSI.2013.10.057
Akitoshi Hayashi, Takamasa Ohtomo, Fuminori Mizuno, Kiyoharu Tadanaga, Masahiro Tatsumisago, Rechargeable lithium batteries, using sulfur-based cathode materials and Li2S–P2S5 glass-ceramic electrolytes Electrochimica Acta. ,vol. 50, pp. 893- 897 ,(2004) , 10.1016/J.ELECTACTA.2004.02.061
Jan Swenson, Stefan Adams, Mixed alkali effect in glasses. Physical Review Letters. ,vol. 90, pp. 155507- ,(2003) , 10.1103/PHYSREVLETT.90.155507
R. P. Rao, S. Adams, Studies of lithium argyrodite solid electrolytes for all‐solid‐state batteries Physica Status Solidi (a). ,vol. 208, pp. 1804- 1807 ,(2011) , 10.1002/PSSA.201001117
R. Prasada Rao, N. Sharma, V.K. Peterson, S. Adams, Formation and conductivity studies of lithium argyrodite solid electrolytes using in-situ neutron diffraction Solid State Ionics. ,vol. 230, pp. 72- 76 ,(2013) , 10.1016/J.SSI.2012.09.014
Hans-Jörg Deiseroth, Shiao-Tong Kong, Hellmut Eckert, Julia Vannahme, Christof Reiner, Torsten Zaiß, Marc Schlosser, Li6PS5X: A Class of Crystalline Li‐Rich Solids With an Unusually High Li+ Mobility Angewandte Chemie. ,vol. 47, pp. 755- 758 ,(2008) , 10.1002/ANIE.200703900
A Haznar, A Pietraszko, I.P Studenyak, X-ray study of the superionic phase transition in Cu6PS5Br Solid State Ionics. ,vol. 119, pp. 31- 36 ,(1999) , 10.1016/S0167-2738(98)00479-2
Sylvain Boulineau, Jean-Marie Tarascon, Jean-Bernard Leriche, Virginie Viallet, Electrochemical properties of all-solid-state lithium secondary batteries using Li-argyrodite Li6PS5Cl as solid electrolyte Solid State Ionics. ,vol. 242, pp. 45- 48 ,(2013) , 10.1016/J.SSI.2013.04.012
J.-S. Chung, H.-J. Sohn, Electrochemical behaviors of CuS as a cathode material for lithium secondary batteries Journal of Power Sources. ,vol. 108, pp. 226- 231 ,(2002) , 10.1016/S0378-7753(02)00024-1