Dissolution behavior of selenium from coal fly ash particles for the development of an acid-washing process

作者: Shunsuke Kashiwakura , Hajime Ohno , Yuichi Kumagai , Hiroshi Kubo , Kazuyo Matsubae

DOI: 10.1016/J.CHEMOSPHERE.2011.06.099

关键词: ArsenicFly ashAdsorptionDissolutionEnvironmental chemistryScientific methodElutionChemistryWaste managementBoronSelenium

摘要: Abstract Coal fly ash emitted from coal-fired electric power stations generally contains environmentally regulated trace elements. In particular, boron, arsenic, and selenium have been recognized as troublesome elements because elutions the contain them. order to design an effective removal process for these elements, we developed investigated acid-washing process. The dissolution behavior of coal particles was focused on improvement process, found greatly depend pH acid solutions. species in solutions with a around 0–1 determined be H2SeO3. dissolved H2SeO3 transformed into HSeO 3 - adsorbed onto surface solution upon elevation pH. re-elution absorbed SeO 2 at 10 also confirmed, will cause elution excess acid-washed ash.

参考文章(20)
Shunsuke Kashiwakura, Takafumi Takahashi, Tetsuya Nagasaka, Vaporization behavior of boron from standard coals in the early stage of combustion Fuel. ,vol. 90, pp. 1408- 1415 ,(2011) , 10.1016/J.FUEL.2010.12.029
Shunsuke Kashiwakura, Takafumi Takahashi, Hideki Maekawa, Tetsuya Nagasaka, Application of 11B MAS-NMR to the characterization of boron in coal fly ash generated from Nantun coal Fuel. ,vol. 89, pp. 1006- 1011 ,(2010) , 10.1016/J.FUEL.2009.10.028
Naoki Noda, Shigeo Ito, The release and behavior of mercury, selenium, and boron in coal combustion Powder Technology. ,vol. 180, pp. 227- 231 ,(2008) , 10.1016/J.POWTEC.2007.03.031
Minghou Xu, Rong Yan, Chuguang Zheng, Yu Qiao, Jun Han, Changdong Sheng, Status of trace element emission in a coal combustion process: a review Fuel Processing Technology. ,vol. 85, pp. 215- 237 ,(2004) , 10.1016/S0378-3820(03)00174-7
Shunsuke Kashiwakura, Hajime Ohno, Kazuyo Matsubae-Yokoyama, Yuichi Kumagai, Hiroshi Kubo, Tetsuya Nagasaka, Removal of arsenic in coal fly ash by acid washing process using dilute H2SO4 solvent. Journal of Hazardous Materials. ,vol. 181, pp. 419- 425 ,(2010) , 10.1016/J.JHAZMAT.2010.05.027
Ruud Meij, Trace element behavior in coal-fired power plants Fuel Processing Technology. ,vol. 39, pp. 199- 217 ,(1994) , 10.1016/0378-3820(94)90180-5
Frank E. Huggins, Constance L. Senior, Paul Chu, Ken Ladwig, Gerald P. Huffman, Selenium and arsenic speciation in fly ash from full-scale coal-burning utility plants Environmental Science & Technology. ,vol. 41, pp. 3284- 3289 ,(2007) , 10.1021/ES062069Y
Kevin C. Galbreath, Donald L. Toman, Christopher J. Zygarlicke, John H. Pavlish, Trace Element Partitioning and Transformations During Combustion of Bituminous and Subbituminous U. S. Coals In a 7-kW Combustion System Energy & Fuels. ,vol. 14, pp. 1265- 1279 ,(2000) , 10.1021/EF000105N
R. Agnihotri, S. Chauk, S. Mahuli, L.-S. Fan, Selenium removal using Ca-based sorbents : Reaction kinetics Environmental Science & Technology. ,vol. 32, pp. 1841- 1846 ,(1998) , 10.1021/ES971119J