Study on acetate ion recognition and sensing in aqueous media using a novel and simple colorimetric sensor and its analytical application.
作者： Jie Shao , Hai Lin , Ming Yu , Zunsheng Cai , Huakuan Lin
DOI: 10.1016/J.TALANTA.2007.11.048
关键词: Analytical chemistry 、 Aqueous solution 、 Colorimetric sensor 、 Aqueous medium 、 Red shift 、 Chemistry 、 Titration 、 Proton NMR 、 Colorimetry 、 Acetate ion
摘要: A new and simple phenylhydrazone-based sensor 1 for acetate has been investigated in DMSO even the 95:5 DMSO/H2O (v/v) mixtures. Binding of anions such as AcO-, F- H2PO4(-) results a noteworthy change visible region spectrum (approximately 100 nm red shift), which can be detected by 'naked-eye'. The further insights to nature interactions between AcO- were 1H NMR titration experiments DMSO-d(6). In particular, analytical application detection ion have also studied aqueous.
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