作者: Peter N. Pusey , J. Michael Vaughan , Graham Williams
DOI: 10.1039/F29747001696
关键词: Diffusion 、 Light scattering 、 Polystyrene 、 Effective diffusion coefficient 、 Cyclohexane 、 Correlation function (statistical mechanics) 、 Exponential decay 、 Analytical chemistry 、 Dynamic light scattering 、 Chemistry
摘要: The diffusion behaviour in toluene, and some cases toluene + cyclohexane mixtures, of three polystyrenes, two narrow molecular weight distribution one broad distribution, has been studied using photon correlation spectroscopy. apparent coefficient text-decoration:overlineD increases with increasing concentration all cases. For a sample the function g(1)(K, τ) shows marked departure from single exponential decay as increases, possible causes this are considered terms theory light scattering process. variation is examined.