Synthesis and characterization of Copper (II) Schiff base complex containing MCM-41 as robust and clean nano reactor catalyst for the selective oxidation of sulfides to sulfoxides using H2O2
作者： Houri Mahdavi , Mohsen Nikoorazm , Arash Ghorbani-Choghamarani , Sattar Arshadi
DOI: 10.1007/S10934-015-0057-Z
关键词: Fourier transform infrared spectroscopy 、 Copper 、 Schiff base 、 Inorganic chemistry 、 Mesoporous silica 、 Heterogeneous catalysis 、 MCM-41 、 Adsorption 、 Catalysis 、 Chemistry
摘要: An efficient and versatile procedure has been introduced for the preparation of copper supported on functionalized mesoporous silica (MCM-41) containing chelating Schiff base salen (the structure this complex was studied by X-ray diffraction, transmission electron microscopy, Fourier transform infrared spectroscopy, thermo gravimetric analysis N2 adsorption desorption), which applied as catalyst conversion various sulfides into sulfoxides with aqueous hydrogen peroxide. Also heterogeneous can be recovered easily reused many times oxidation without significant loss activity selectivity.
springer.com
sci-hub.se 参考文章(31)
Arash Ghorbani-Choghamarani, Zahra Darvishnejad, Masoomeh Norouzi, Cu(II)–Schiff base complex‐functionalized magnetic Fe3O4 nanoparticles: a heterogeneous catalyst for various oxidation reactions Applied Organometallic Chemistry. ,vol. 29, pp. 170- 175 ,(2015) , 10.1002/AOC.3266
Yolanda Pérez, Ruth Ballesteros, Mariano Fajardo, Isabel Sierra, Isabel del Hierro, Copper-containing catalysts for solvent-free selective oxidation of benzyl alcohol Journal of Molecular Catalysis A-chemical. ,vol. 352, pp. 45- 56 ,(2012) , 10.1016/J.MOLCATA.2011.10.009
Samit Majumder, Susanta Hazra, Supriya Dutta, Papu Biswas, Sasankasekhar Mohanta, Syntheses, structures and electrochemistry of manganese(III) complexes derived from N,N′-o-phenylenebis(3-ethoxysalicylaldimine): Efficient catalyst for styrene epoxidation Polyhedron. ,vol. 28, pp. 2473- 2479 ,(2009) , 10.1016/J.POLY.2009.04.034
Zolfaghar Rezvani, Mohammad Ali Ghanea, Kamellia Nejati, Sara Abodollahzadeh Baghaei, Syntheses and mesomorphic properties of new oxygen-bridged dicopper complex homologous derived from azo-containing salicylaldimine Schiff base ligands Polyhedron. ,vol. 28, pp. 2913- 2918 ,(2009) , 10.1016/J.POLY.2009.06.089
Mojtaba Bagherzadeh, Laleh Tahsini, Reza Latifi, Efficient oxidation of olefins and sulfides catalyzed by manganese(III)-tridentate Schiff base complex using UHP as oxidant Catalysis Communications. ,vol. 9, pp. 1600- 1606 ,(2008) , 10.1016/J.CATCOM.2008.01.020
J. Evans, A. B. Zaki, M. Y. El-Sheikh, S. A. El-Safty, Incorporation of Transition-Metal Complexes in Functionalized Mesoporous Silica and Their Activity toward the Oxidation of Aromatic Amines Journal of Physical Chemistry B. ,vol. 104, pp. 10271- 10281 ,(2000) , 10.1021/JP000564P
Huajun Zheng, Zuo Chen, Limin Wang, Chun’an Ma, Synthesis, characterization and catalytic activity toward methanol oxidation of electrocatalyst Pt4+-NH2-MCM-41 Electrochimica Acta. ,vol. 83, pp. 160- 165 ,(2012) , 10.1016/J.ELECTACTA.2012.08.011
Hakan Dumrul, Ahmed Nuri Kursunlu, Ozcan Kocyigit, Ersin Guler, Seref Ertul, Adsorptive removal of Cu(II) and Ni(II) ions from aqueous media by chemical immobilization of three different aldehydes Desalination. ,vol. 271, pp. 92- 99 ,(2011) , 10.1016/J.DESAL.2010.12.017
Arash Ghorbani-Choghamarani, Maryam Hajjami, Hamid Goudarziafshar, Mohsen Nikoorazm, Shadpour Mallakpour, Fatemeh Sadeghizadeh, Gouhar Azadi, Catalytic oxidation of urazoles and bis-urazoles to their corresponding triazolinediones using aluminium nitrate and a catalytic amount of silica sulfuric acid Monatshefte für Chemie - Chemical Monthly. ,vol. 140, pp. 607- 610 ,(2009) , 10.1007/S00706-008-0100-8
Enrico Baciocchi, Cinzia Chiappe, Tiziana Del Giacco, Chiara Fasciani, Osvaldo Lanzalunga, Andrea Lapi, Bernardo Melai, Reaction of singlet oxygen with thioanisole in ionic liquids: a solvent induced mechanistic dichotomy. Organic Letters. ,vol. 11, pp. 1413- 1416 ,(2009) , 10.1021/OL900140W