The Mechanism of Aminations of Halobenzenes
作者： John D. Roberts , Dorothy A. Semenow , Howard E. Simmons , L. A. Carlsmith
DOI: 10.1021/JA01584A024
关键词: Photochemistry 、 Halide 、 Metal 、 Aryne 、 Aryl 、 Atom 、 Halogen 、 Hydrogen atom 、 Chemistry
摘要: An elimination-addition mechanism, probably involving a "benzyne" intermediate, has been established for the rearrangements which often occur in conversion of non-activated aryl halides to arylamines with metallic amides. The evidence intermediate was obtained through ^(14)C-tracer studies halobenzenes and experiments designed determine role hydrogen atom located ortho displaced halogen atom.
acs.org
sci-hub.se 参考文章(0)