Kinetic modeling of catalytic cracking of C4 alkanes over La/HZSM-5 catalysts in light olefin production
作者： Nazi Rahimi , Ramin Karimzadeh
DOI: 10.1016/J.JAAP.2015.08.004
关键词: Elementary reaction 、 Plug flow reactor model 、 Butane 、 Alkane 、 Inorganic chemistry 、 Cracking 、 Fluid catalytic cracking 、 Catalysis 、 Physical chemistry 、 Chemistry 、 Reaction rate
摘要: Abstract Kinetic modeling of catalytic cracking (CC) C4 alkanes (mixture i-butane and n-butane), over Lanthanum modified HZSM-5 catalyst has been studied at 582–630 °C in a plug flow reactor. The elementary reaction steps, i.e., protolytic (PC) C H bonds alkane molecules, hydrogen transfer between butane light olefins, olefin cracking, β-scission, adsorption desorption were taken into account. combination theory routes LHHW employed the complicated CC network to drive explicit overall rate reactantand product molecules. Then, parameter estimation model discrimination performed based on minimization mean residual sum squares experimental theoretical rates. intrinsic kinetic parameters estimated by non-linear least-square regression using MATLAB optimization toolbox.
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sci-hub.se 参考文章(43)
Y. Yoshimura, N. Kijima, T. Hayakawa, K. Murata, K. Suzuki, F. Mizukami, K. Matano, T. Konishi, T. Oikawa, M. Saito, T. Shiojima, K. Shiozawa, K. Wakui, G. Sawada, K. Sato, S. Matsuo, N. Yamaoka, Catalytic Cracking of Naphtha to Light Olefins Catalysis Surveys From Japan. ,vol. 4, pp. 157- 167 ,(2001) , 10.1023/A:1011463606189
Sang Yun Han, Chul Wee Lee, Jeong Ri Kim, Nam Sun Han, Won Choon Choi, Chae-Ho Shin, Yong-Ki Park, Selective Formation of Light Olefins by the Cracking of Heavy Naphtha over Acid Catalysts Studies in Surface Science and Catalysis. ,vol. 153, pp. 157- 160 ,(2004) , 10.1016/S0167-2991(04)80237-4
Combinatorial catalysis and high throughput catalyst design and testing Kluwer Academic Publishers. ,(2000) , 10.1007/978-94-011-4329-5
Y. Wei, Z. Liu, G. Wang, Y. Qi, L. Xu, P. Xie, Y. He, Production of light olefins and aromatic hydrocarbons through catalytic cracking of naphtha at lowered temperature Studies in Surface Science and Catalysis. ,vol. 158, pp. 1223- 1230 ,(2005) , 10.1016/S0167-2991(05)80468-9
Dmitri B. Lukyanov, Application of a kinetic model for investigation of aromatization reactions of light paraffins and olefins over HZSM-5 Studies in Surface Science and Catalysis. ,vol. 105, pp. 1301- 1308 ,(1997) , 10.1016/S0167-2991(97)80770-7
Gilbert F. Froment, Kenneth B. Bischoff, Juray De Wilde, Chemical Reactor Analysis and Design ,(1979)
Nazi Rahimi, Ramin Karimzadeh, Catalytic cracking of hydrocarbons over modified ZSM-5 zeolites to produce light olefins: A review Applied Catalysis A-general. ,vol. 398, pp. 1- 17 ,(2011) , 10.1016/J.APCATA.2011.03.009
Diana Mier, Andrés T. Aguayo, Mónica Gamero, Ana G. Gayubo, Javier Bilbao, Kinetic Modeling of n-Butane Cracking on HZSM-5 Zeolite Catalyst Industrial & Engineering Chemistry Research. ,vol. 49, pp. 8415- 8423 ,(2010) , 10.1021/IE1006245
A. Corma, A.V. Orchillés, Current views on the mechanism of catalytic cracking Microporous and Mesoporous Materials. ,vol. 35, pp. 21- 30 ,(2000) , 10.1016/S1387-1811(99)00205-X
Ville Nieminen, Matias Kangas, Tapio Salmi, Dmitry Yu. Murzin, Kinetic Study of n-Butane Isomerization over Pt−H-Mordenite Industrial & Engineering Chemistry Research. ,vol. 44, pp. 471- 484 ,(2005) , 10.1021/IE049544Q