Iodine-Based Reagents in Oxidative Amination and Oxygenation
作者： Kensuke Kiyokawa , Satoshi Minakata
关键词: Iodine 、 Radical 、 Reagent 、 Organic chemistry 、 Primary (chemistry) 、 Functional group 、 Chemistry 、 Reactivity (chemistry) 、 Amination 、 Hypervalent molecule
摘要: In this Account, we provide an overview of our recent advances in oxidative transformations that enable the introduction nitrogen and oxygen functionalities into organic molecules by taking advantage unique characteristics iodine-based reagents, such as hypervalency, soft Lewis acidity, high leaving ability, radical reactivity. We also report on development new types hypervalent iodine reagents containing a transferable functional group with objective preparing primary amines, which is described latter part Account. 1 Introduction 2 Decarboxylative Functionalization β,γ-Unsaturated Carboxylic Acids 3 at Tertiary Carbon Centers 4 C–H Bond 5 Intramolecular C–H Amination Sulfamate Esters N-Alkylsulfamides 6 Oxidative Hypervalent Iodine Reagents Containing Transferable Nitrogen Functional Groups 7 Summary Outlook
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