Quantum Dots in Visible-Light Photoredox Catalysis: Reductive Dehalogenations and C–H Arylation Reactions Using Aryl Bromides

作者: Anuushka Pal , Indrajit Ghosh , Sameer Sapra , Burkhard König

DOI: 10.1021/ACS.CHEMMATER.7B01109

关键词: PhotochemistryRedoxHalogenationSpecific surface areaChemistryChemical bondArylQuantum dotCatalysisPhotoredox catalysis

摘要: … the generation of highly reactive aryl or heteroaryl radicals from their corresponding halides … core/shell QDs and visible light. Upon single electron transfer, (hetero)aryl halides (Ar−X, …

参考文章(57)
Anuushka Pal, Parveen Saini, Sameer Sapra, Conjugated-Polymer/Quantum-Confined Nanomaterials-Based Hybrids for Optoelectronic Applications Fundamentals of Conjugated Polymer Blends, Copolymers and Composites. pp. 163- 227 ,(2015) , 10.1002/9781119137160.CH3
Daisuke Tanaka, Yuya Oaki, Hiroaki Imai, Enhanced photocatalytic activity of quantum-confined tungsten trioxide nanoparticles in mesoporous silica Chemical Communications. ,vol. 46, pp. 5286- 5288 ,(2010) , 10.1039/C0CC00540A
Roberto A. Rossi, Adriana B. Pierini, Alicia B. Peñéñory, Nucleophilic substitution reactions by electron transfer Chemical Reviews. ,vol. 103, pp. 71- 167 ,(2003) , 10.1021/CR960134O
Alexander Nemchinov, Maria Kirsanova, Nishshanka N. Hewa-Kasakarage, Mikhail Zamkov, Synthesis And Characterization Of Type II ZnSe/ CdS Core/Shell Nanocrystals Journal of Physical Chemistry C. ,vol. 112, pp. 9301- 9307 ,(2008) , 10.1021/JP801523M
E. Pelizzetti, C. Minero, Mechanism of the photo-oxidative degradation of organic pollutants over TiO2 particles Electrochimica Acta. ,vol. 38, pp. 47- 55 ,(1993) , 10.1016/0013-4686(93)80009-O
Bin Liu, Xu-Bing Li, Yu-Ji Gao, Zhi-Jun Li, Qing-Yuan Meng, Chen-Ho Tung, Li-Zhu Wu, A solution-processed, mercaptoacetic acid-engineered CdSe quantum dot photocathode for efficient hydrogen production under visible light irradiation Energy and Environmental Science. ,vol. 8, pp. 1443- 1449 ,(2015) , 10.1039/C5EE00331H
Cyrille Costentin, Marc Robert, Jean-Michel Savéant, Fragmentation of Aryl Halide π Anion Radicals. Bending of the Cleaving Bond and Activation vs Driving Force Relationships Journal of the American Chemical Society. ,vol. 126, pp. 16051- 16057 ,(2004) , 10.1021/JA045989U
Gerasimos Konstantatos, Ian Howard, Armin Fischer, Sjoerd Hoogland, Jason Clifford, Ethan Klem, Larissa Levina, Edward H. Sargent, Ultrasensitive solution-cast quantum dot photodetectors Nature. ,vol. 442, pp. 180- 183 ,(2006) , 10.1038/NATURE04855
Zhigang Zou, Jinhua Ye, Kazuhiro Sayama, Hironori Arakawa, Direct splitting of water under visible light irradiation with an oxide semiconductor photocatalyst Nature. ,vol. 414, pp. 625- 627 ,(2001) , 10.1038/414625A