Polymer molecular-weight distribution from dynamic melt viscoelasticity
作者： Souhenc Wu
关键词: Gel permeation chromatography 、 Molar mass distribution 、 Analytical chemistry 、 Polymer chemistry 、 Polymer 、 Materials science 、 Viscoelasticity 、 Dispersity 、 Osmometer 、 Size-exclusion chromatography 、 Light scattering 、 Materials Chemistry 、 General chemistry 、 Polymers and Plastics
摘要: A method is developed by which polymer molecular weight and its distribution can be accurately determined deconvolution of dynamic melt viscoelastic properties in the terminal plateau zones. The illustrated with a series monodisperse (narrow-distribution) polydisperse (broaddistribution) polystyrenes. Mn, Mw, Mn/Mw values obtained are excellent agreement those light scattering, osmometry gel permeation chromatography less than 5 to 10 percent error. differential molecular-weight curves coincide wall chromatography. applicable insoluble as well soluble polymers.
sci-hub.se 参考文章(16)
William W. Graessley, Entangled linear, branched and network polymer systems — Molecular theories Synthesis and Degradation Rheology and Extrusion. ,vol. 47, pp. 67- 117 ,(1982) , 10.1007/BFB0038532
William W. Graessley, The entanglement concept in polymer rheology Springer Berlin Heidelberg. pp. 1- 179 ,(1974) , 10.1007/BFB0031037
Masao Doi, S. F. Edwards, Dynamics of concentrated polymer systems. Part 3.—The constitutive equation Journal of the Chemical Society, Faraday Transactions. ,vol. 74, pp. 1818- 1832 ,(1978) , 10.1039/F29787401818
E. Menefee, Polydisperse polymers: Relations among molecular weight distribution, stress relaxation, and distribution of relaxation times Journal of Applied Polymer Science. ,vol. 16, pp. 2215- 2238 ,(1972) , 10.1002/APP.1972.070160906
Kazuhiko Ninomiya, Effects of blending on the stress-relaxation behavior of polyvinyl acetate in the rubbery region Journal of Colloid Science. ,vol. 14, pp. 49- 58 ,(1959) , 10.1016/0095-8522(59)90068-6
Shigehara Onogi, Toshiro Masuda, Keishi Kitagawa, Rheological Properties of Anionic Polystyrenes. I. Dynamic Viscoelasticity of Narrow-Distribution Polystyrenes Macromolecules. ,vol. 3, pp. 109- 116 ,(1970) , 10.1021/MA60014A001
Masao Doi, S. F. Edwards, Dynamics of concentrated polymer systems. Part 2.—Molecular motion under flow Journal of the Chemical Society, Faraday Transactions. ,vol. 74, pp. 1802- 1817 ,(1978) , 10.1039/F29787401802
Donald C Bogue, Toshiro Masuda, Yoshiyuki Einaga, Shigeharu Onogi, A Constitutive Model for Molecular Weight and Concentration Effects in Polymer Blends Polymer Journal. ,vol. 1, pp. 563- 572 ,(1970) , 10.1295/POLYMJ.1.563
Masao Doi, S. F. Edwards, Dynamics of concentrated polymer systems. Part 4.—Rheological properties Journal of the Chemical Society, Faraday Transactions. ,vol. 75, pp. 38- 54 ,(1979) , 10.1039/F29797500038
N. W. Tschoegl, A general method for the determination of approximations to the spectral distributions from the dynamic response functions Rheologica Acta. ,vol. 10, pp. 582- 594 ,(1971) , 10.1007/BF01526904