Scale deposits in tunnel drainage systems – A study on fabrics and formation mechanisms

作者: Stefanie Eichinger , Ronny Boch , Albrecht Leis , Günther Koraimann , Cyrill Grengg

DOI: 10.1016/J.SCITOTENV.2020.137140

关键词: SupersaturationCalciteChemistryAqueous solutionAragoniteAquiferDypingitePrecipitation (chemistry)Calcium carbonateMineralogy

摘要: Abstract Rapid deposition of chemical sediments, particularly calcium carbonate, is a widespread phenomenon in tunnel constructions, which can significantly disturb water draining. The removal the scale deposits drainage setting labor and cost intensive. Prediction or prevention these unwanted are challenging require detailed knowledge on their site-specific source, formation mechanisms environmental dependencies. This case study combines mineralogical, (micro)structural, isotopic, microbiological, hydrochemical approach to understand an Austrian motorway tunnel. Chemical isotopic results revealed that all investigated solutions originate from distinct local aquifer. High pH (11), indicative high alkaline element concentrations (Na 26 mg/l; K 67 mg/l), originated concrete leaching, strong supersaturation respect calcite (SI > 1) representative for scaling type 1. characterized by calcite, aragonite, rarely documented dypingite (Mg5(CO3)4(OH)2*5H2O), yields highly porous material showing minor indications microbial presence. In contrast, 2 strongly microbially influenced, yielding dense layered mineral deposits, typically consisting calcite. corresponding aqueous solution elevated Mg concentration (38 mg/l) molar Mg/Ca ratio (0.8). Scale containing aragonite precipitates next mostly growing pore spaces fabric, accounted as 3. Therein, always top needles, prior CaCO3 precipitation. composition shows highest (1.1). 4 compact deposit entirely Its exhibits 0.6. From obtained data sets conceptual model was developed describing operative (micro)environmental conditions responsible diversity deposits.

参考文章(76)
M. Dietzel, T. Rinder, A. Niedermayr, F. Mittermayr, A. Leis, D. Klammer, S. Köhler, P. Reichl, Ursachen und Mechanismen der Versinterung von Tunneldrainagen BHM Berg- und Hüttenmännische Monatshefte. ,vol. 153, pp. 369- 372 ,(2008) , 10.1007/S00501-008-0412-3
A. E. Vatter, R. S. Wolfe, ELECTRON MICROSCOPY OF GALLIONELLA FERRUGINEA1 Journal of Bacteriology. ,vol. 72, pp. 248- 252 ,(1956) , 10.1128/JB.72.2.248-252.1956
Jochen Hoefs, Theoretical and Experimental Principles Springer, Berlin, Heidelberg. pp. 1- 46 ,(2015) , 10.1007/978-3-319-19716-6_1
David Mattey, D. Lowry, J. Duffet, R. Fisher, E. Hodge, S. Frisia, A 53 year seasonally resolved oxygen and carbon isotope record from a modern Gibraltar speleothem: Reconstructed drip water and relationship to local precipitation Earth and Planetary Science Letters. ,vol. 269, pp. 80- 95 ,(2008) , 10.1016/J.EPSL.2008.01.051
Martin Dietzel, Thorsten Kirchhoff, Stable Isotope Ratios and the Evolution of Acidulous Ground Water Aquatic Geochemistry. ,vol. 8, pp. 229- 254 ,(2002) , 10.1023/B:AQUA.0000003724.43004.1E
Yiming Huang, Ian J Fairchild, Partitioning of Sr2+ and Mg2+ into calcite under karst-analogue experimental conditions Geochimica et Cosmochimica Acta. ,vol. 65, pp. 47- 62 ,(2001) , 10.1016/S0016-7037(00)00513-5
Henry S Chafetz, Sean A Guidry, Bacterial shrubs, crystal shrubs, and ray-crystal shrubs: bacterial vs. abiotic precipitation Sedimentary Geology. ,vol. 126, pp. 57- 74 ,(1999) , 10.1016/S0037-0738(99)00032-9
Peter Onuk, Martin Dietzel, Christoph Anton Hauzenberger, Formation of helictite in the cave Dragon Belly (Sardinia, Italy)—Microstructure and incorporation of Mg, Sr, and Ba Geochemistry. ,vol. 74, pp. 443- 452 ,(2014) , 10.1016/J.CHEMER.2014.04.003
Thomas Rinder, Martin Dietzel, Albrecht Leis, Calcium carbonate scaling under alkaline conditions – Case studies and hydrochemical modelling Applied Geochemistry. ,vol. 35, pp. 132- 141 ,(2013) , 10.1016/J.APGEOCHEM.2013.03.019