Functionalized methanofullerenes used as n-type materials in bulk-heterojunction polymer solar cells and in field-effect transistors.
作者： Changduk Yang , Jin Young Kim , Shinuk Cho , Jae Kwan Lee , Alan J. Heeger
DOI: 10.1021/JA710621J
关键词: Buckminsterfullerene 、 Photoinduced electron transfer 、 Thin-film transistor 、 Alkoxy group 、 Polymer solar cell 、 Organic chemistry 、 Side chain 、 Chemistry 、 Open-circuit voltage 、 Chemical engineering 、 Organic solar cell
摘要: The synthesis of two well-solubilized [60]methanofullerene derivatives (p-EHO-PCBM and p-EHO-PCBA) is presented for usage in organic solar cells field-effect transistors. para position the PCBM’s phenyl ring was substituted with a branched alkoxy side chain, which contributes to higher solubility, facilitating synthesis, purification, processing. We find small change open-circuit voltage (Voc) as slight improvement performance upon application P3HT/[60]methanofullerene bulk-heterojunction-photovoltaic cells, when compared PCBM, because electron donation group. In case devices TiOx layer, best power conversion efficiencies (PCE, ηe) observed layered structure P3HT/p-EHO-PCBA/TiOx (ηe = 2.6%), slightly exceeds that P3HT/PCBM/TiOx 2.3%) under conditions reported here. This can be attributed, part, carboxylic acid group p-EHO-PCBA leads an effective interface interaction between ...
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sci-hub.se 参考文章(28)
R. C. Haddon, C70 THIN FILM TRANSISTORS Journal of the American Chemical Society. ,vol. 118, pp. 3041- 3042 ,(1996) , 10.1021/JA953881W
N. Camaioni, G. Ridolfi, G. Casalbore-Miceli, G. Possamai, M. Maggini, The Effect of a Mild Thermal Treatment on the Performance of Poly(3‐alkylthiophene)/Fullerene Solar Cells Advanced Materials. ,vol. 14, pp. 1735- 1738 ,(2002) , 10.1002/1521-4095(20021203)14:23<1735::AID-ADMA1735>3.0.CO;2-O
Toshiyasu Suzuki, Yusei Maruyama, Takeshi Akasaka, Wataru Ando, Kaoru Kobayashi, Shigeru Nagase, Redox properties of organofullerenes Journal of the American Chemical Society. ,vol. 116, pp. 1359- 1363 ,(1994) , 10.1021/JA00083A022
R. C. Haddon, Chemistry of the fullerenes: the manifestation of strain in a class of continuous aromatic molecules. Science. ,vol. 261, pp. 1545- 1550 ,(1993) , 10.1126/SCIENCE.261.5128.1545
Jacques. Moser, Swarnalatha. Punchihewa, Pierre P. Infelta, Michael. Graetzel, Surface complexation of colloidal semiconductors strongly enhances interfacial electron-transfer rates Langmuir. ,vol. 7, pp. 3012- 3018 ,(1991) , 10.1021/LA00060A018
C Anderson, AZT patent. Court favors drug 'concept' over proof. Science. ,vol. 261, pp. 545- 545 ,(1993) , 10.1126/SCIENCE.8342014
W. Ma, C. Yang, X. Gong, K. Lee, A. J. Heeger, Thermally stable, efficient polymer solar cells with nanoscale control of the interpenetrating network morphology Advanced Functional Materials. ,vol. 15, pp. 1617- 1622 ,(2005) , 10.1002/ADFM.200500211
Jun-ichi Nakamura, Kazuhiko Murata, Kohshin Takahashi, Relation between carrier mobility and cell performance in bulk heterojunction solar cells consisting of soluble polythiophene and fullerene derivatives Applied Physics Letters. ,vol. 87, pp. 132105- ,(2005) , 10.1063/1.2058210
Floris B. Kooistra, Joop Knol, Fredrik Kastenberg, Lacramioara M. Popescu, Wiljan J. H. Verhees, Jan M. Kroon, Jan C. Hummelen, Increasing the Open Circuit Voltage of Bulk-Heterojunction Solar Cells by Raising the LUMO Level of the Acceptor Organic Letters. ,vol. 9, pp. 551- 554 ,(2007) , 10.1021/OL062666P
C. J. Brabec, A. Cravino, D. Meissner, N. S. Sariciftci, T. Fromherz, M. T. Rispens, L. Sanchez, J. C. Hummelen, Origin of the Open Circuit Voltage of Plastic Solar Cells Advanced Functional Materials. ,vol. 11, pp. 374- 380 ,(2001) , 10.1002/1616-3028(200110)11:5<374::AID-ADFM374>3.0.CO;2-W