Optimization of electrochemical properties of LiFePO4/C prepared by an aqueous solution method using sucrose

作者: Yoshihiro Kadoma , Jung-Min Kim , Katsutoshi Abiko , Keitaro Ohtsuki , Koichi Ui

DOI: 10.1016/J.ELECTACTA.2009.09.029

关键词: Soft chemistryVolumetric flow rateElectrochemistryAqueous solutionComposite numberAnalytical chemistryChemical engineeringCarbonPyrolysisQuaternary compoundChemistry

摘要: LiFePO4 can be used as a positive electrode material for lithium-ion batteries by making composite with electrical conductive carbonaceous materials. In this study, LiFePO4/C (carbon) was prepared soft chemistry route, in which sucrose carbon source of low price. We tried to optimize Li/(LiFePO4/C) cell performance through changing synthetic conditions and discussed the factors affecting electrochemical performances cell, such amount source, temperature, gas flow rate pyrolysis formation secondary phases. It found that connection residual Fe2P particles these two phases were important factors. our experimental conditions, including 9.72 wt.% carbon, at 800 °C 12 h showed highest reversible capacity best C among synthesized materials; 130 mAh g−1 10C 50 °C.

参考文章(32)
A. Yamada, M. Hosoya, S. C. Chung, K. Hinokuma, Y. Kudo, K.Y. Liu, Olivine-Type Cathodes for Lithium Batteries Ceramic transactions. ,vol. 127, pp. 189- 203 ,(2012) , 10.1002/9781118370858.CH20
Tatsuya Nakamura, Kiyotaka Sakumoto, Shiro Seki, Yo Kobayashi, Mitsuharu Tabuchi, Yoshihiro Yamada, Apparent Diffusion Constant and Electrochemical Reaction in LiFe1 − x Mn x PO4 Olivine Cathodes Journal of The Electrochemical Society. ,vol. 154, ,(2007) , 10.1149/1.2790803
G. X. Wang, S. Bewlay, S. A. Needham, H. K. Liu, R. S. Liu, V. A. Drozd, J.-F. Lee, J. M. Chen, Synthesis and characterization of LiFePO4 and LiTi0.01Fe0.99PO4 cathode materials Journal of The Electrochemical Society. ,vol. 153, ,(2006) , 10.1149/1.2128766
Marca M. Doeff, Yaoqin Hu, Frank McLarnon, Robert Kostecki, Effect of surface carbon structure on the electrochemical performance of LiFePO{sub 4} Electrochemical and Solid State Letters. ,vol. 6, ,(2003) , 10.1149/1.1601372
Y ‐W. Hu, I. D. Raistrick, R. A. Huggins, Ionic Conductivity of Lithium Orthosilicate—Lithium Phosphate Solid Solutions Journal of The Electrochemical Society. ,vol. 124, pp. 1240- 1242 ,(1977) , 10.1149/1.2133537
N. Ravet, Y. Chouinard, J.F. Magnan, S. Besner, M. Gauthier, M. Armand, Electroactivity of natural and synthetic triphylite Journal of Power Sources. ,vol. 97, pp. 503- 507 ,(2001) , 10.1016/S0378-7753(01)00727-3
Hoon-Taek Chung, Soo-Kwan Jang, Han Wool Ryu, Kwang-Bo Shim, Effects of nano-carbon webs on the electrochemical properties in LiFePO4/C composite Solid State Communications. ,vol. 131, pp. 549- 554 ,(2004) , 10.1016/J.SSC.2004.03.010
Seung-Taek Myung, Shinichi Komaba, Norimitsu Hirosaki, Hitoshi Yashiro, Naoaki Kumagai, Emulsion drying synthesis of olivine LiFePO4/C composite and its electrochemical properties as lithium intercalation material Electrochimica Acta. ,vol. 49, pp. 4213- 4222 ,(2004) , 10.1016/J.ELECTACTA.2004.04.016
Marie Herstedt, Mårten Stjerndahl, Anton Nytén, Torbjörn Gustafsson, Håkan Rensmo, Hans Siegbahn, Nathalie Ravet, Michel Armand, John O. Thomas, Kristina Edström, Surface chemistry of carbon-treated LiFePO4 particles for Li-ion battery cathodes studied by PES Electrochemical and Solid State Letters. ,vol. 6, ,(2003) , 10.1149/1.1594413
H. Huang, S.-C. Yin, L. F. Nazar, Approaching Theoretical Capacity of LiFePO4 at Room Temperature at High Rates Electrochemical and Solid State Letters. ,vol. 4, pp. 170- 172 ,(2001) , 10.1149/1.1396695