Mössbauer and magnetization study of the mixed spinel CoFe2−xCrxO4

作者: H. Mohan , I.A. Shaikh , R.G. Kulkarni

DOI: 10.1016/0038-1098(92)90717-N

关键词: Nuclear magnetic resonanceFerrimagnetismExchange interactionCondensed matter physicsSpinelPhase (matter)ChemistryPercolationMagnetizationMagnetic structureMössbauer spectroscopy

摘要: Abstract Mossbauer and magnetization measurements are performed at 300 K on the mixed spinel CoFe2−xCrxO4 with a selective Fe-dilution of B-sublattice increasing Cr concentration X from 0 to 1. Magnetization results for = 1 exhibit collinear ferrimagnetic structure, while indicate that B-sublattice, phase breaks down > 0.8 before reaching percolation limit as result presence competing exchange interactions. These explained in terms Villain's model.

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