Iron Catalysis in Synthetic Chemistry

作者: Sujoy Rana , Atanu Modak , Soham Maity , Tuhin Patra , Debabrata Maiti

DOI: 10.1002/9781118869994.CH01

关键词: Chemical synthesisReaction mechanismOrganic chemistryOrganic reactionCoupling reactionEnantioselective synthesisAddition reactionCatalysisOrganic synthesisChemistry

摘要: During the last few decades, transition metal catalysts, especially those on precious metals have proven to be efficient for a large number of applications. Due its abundance, inexpensiveness, and environmentally benign nature, use iron has increased significantly in two decades synthetic transformation both asymmetric synthesis reaction methodology. This development encouraged summarize catalysis organic synthesis, which includes cycloadditions, CC, CN bond formation, redox, other reactions. Trifluoromethylated cyclopropanes are important compounds drug delivery, though very methods were reported their preparation. chapter been divided into different sections based type. It discusses that iron‐catalyzed cross‐coupling mechanism is versatile varies with nature coupling partners condition. Sulfoxides an class since they used various ligand syntheses.

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