Pitfalls in the Use of Solubility Limits for Radioactive Waste Disposal: The Case of Nickel in Sulfidic Groundwaters

作者: Tres Thoenen

DOI: 10.13182/NT99-A2959

关键词: SulfideRadioactive wasteSolubilitySphaleriteNickelEnvironmental chemistryMilleriteSolubility equilibriumChemistryMineralogyRadionuclide

摘要: Solubility limitation of radionuclides by solid phases in aqueous environments is a key factor in performance assessment of radioactive waste repositories. Although the modeling of …

参考文章(40)
John W. Morse, Takeshi Arakaki, Adsorption and coprecipitation of divalent metals with mackinawite (FeS) Geochimica et Cosmochimica Acta. ,vol. 57, pp. 3635- 3640 ,(1993) , 10.1016/0016-7037(93)90145-M
Lucinda Jacobs, Steven Emerson, Jens Skei, Partitioning and transport of metals across the O2H2S interface in a permanently anoxic basin: Framvaren Fjord, Norway☆ Geochimica et Cosmochimica Acta. ,vol. 49, pp. 1433- 1444 ,(1985) , 10.1016/0016-7037(85)90293-5
A. Thiel, H. Gessner, Über Nickelsulfid und Kobaltsulfid. I. Die scheinbare Anomalie im Verhalten des Nickelsulfids gegen Säure Zeitschrift für anorganische und allgemeine Chemie. ,vol. 86, pp. 1- 57 ,(1914) , 10.1002/ZAAC.19140860102
H. Irving, R. J. P. Williams, 637. The stability of transition-metal complexes Journal of the Chemical Society (Resumed). pp. 3192- 3210 ,(1953) , 10.1039/JR9530003192
E. H. Nickel, P. D. Allchurch, M. G. Mason, J. R. Wilmshurst, Supergene alteration at the Perseverance nickel deposit, Agnew, Western Australia Economic Geology. ,vol. 72, pp. 184- 203 ,(1977) , 10.2113/GSECONGEO.72.2.184
Joseph H. Carney, H. A. Laitinen, Electrochemical study of exchange reactions of mercuric sulfide monolayers Analytical Chemistry. ,vol. 42, pp. 473- 478 ,(1970) , 10.1021/AC60286A003
F.G. Ferris, W.S. Fyfe, T.J. Beveridge, Bacteria as nucleation sites for authigenic minerals in a metal-contaminated lake sediment Chemical Geology. ,vol. 63, pp. 225- 232 ,(1987) , 10.1016/0009-2541(87)90165-3
David Dyrssen, Klaus Kremling, Increasing hydrogen sulfide concentration and trace metal behavior in the anoxic Baltic waters Marine Chemistry. ,vol. 30, pp. 193- 204 ,(1990) , 10.1016/0304-4203(90)90070-S
BRIAN MASON, Composition of the Earth Nature. ,vol. 211, pp. 616- 618 ,(1966) , 10.1038/211616A0