Formation of sheets and coating films from alkoxide solutions
作者： S. Sakka , K. Kamiya , K. Makita , Y. Yamamoto
DOI: 10.1016/0022-3093(84)90401-0
关键词: Composite material 、 Coating 、 Hydrolysis 、 Transition metal 、 Linear polymer 、 Spin coating 、 Materials science 、 Dip-coating 、 Alkoxide 、 Polymerization
摘要: Abstract Fundamental problems in preparing thin sheets and coating films of oxides have been discussed on the basis experiments made author's laboratory. It has found that sheet formation is only possible with starting solutions exhibiting spinnability course hydrolysis polymerization metal alkoxide. This requirement satisfied by linear polymers solution. Coating prepared dip-withdrawal technique. 0.05–0.5 μm thickness can be provided one dip-coating run repetition application leads to thicker films. The preparation SiO2, BaTiO3 transition oxide-SiO2 discussed.
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sci-hub.se 参考文章(8)
K. S. MAZDIYASNI, R. T. DOLLOFF, J. S. SMITH, Preparation of High-Purity Submicron Barium Titanate Powders Journal of the American Ceramic Society. ,vol. 52, pp. 523- 526 ,(1969) , 10.1111/J.1151-2916.1969.TB09157.X
Helmut Dislich, Eckart Hussmann, Amorphous and crystalline dip coatings obtained from organometallic solutions: Procedures, chemical processes and products Thin Solid Films. ,vol. 77, pp. 129- 140 ,(1981) , 10.1016/0040-6090(81)90369-2
Charles W. Lentz, Silicate Minerals as Sources of Trimethylsilyl Silicates and Silicate Structure Analysis of Sodium Silicate Solutions Inorganic Chemistry. ,vol. 3, pp. 574- 579 ,(1964) , 10.1021/IC50014A029
PETER C. SCHULTZ, Optical Absorption of the Transition Elements in Vitreous Silica Journal of the American Ceramic Society. ,vol. 57, pp. 309- 313 ,(1974) , 10.1111/J.1151-2916.1974.TB10908.X
Chung-Ching Yang, Jack Y. Josefowicz, Lupu Alexandru, Deposition of ultrathin films by a withdrawal method Thin Solid Films. ,vol. 74, pp. 117- 127 ,(1980) , 10.1016/0040-6090(80)90446-0
S. Sakka, K. Kamiya, The sol-gel transition in the hydrolysis of metal alkoxides in relation to the formation of glass fibers and films Journal of Non-crystalline Solids. ,vol. 48, pp. 31- 46 ,(1982) , 10.1016/0022-3093(82)90244-7
C.R. Masson, Anionic constitution of glass-forming melts Journal of Non-crystalline Solids. ,vol. 25, pp. 1- 41 ,(1977) , 10.1016/0022-3093(77)90089-8
Sumio Sakka, Kanichi Kamiya, Glasses from metal alcoholates Journal of Non-crystalline Solids. ,vol. 42, pp. 403- 421 ,(1980) , 10.1016/0022-3093(80)90040-X