Graphitization of carbon-based catalyst for improving the performance of negative electrode in vanadium redox flow battery

作者: Yungui Chen , Rui Tang , Xumei Cui , Bingxue Hou , Qi Zhang

DOI: 10.1088/2053-1591/ABF6F8

关键词: CarbonRedoxMaterials scienceVanadiumChemical engineeringCatalysisElectrodeFlow battery

摘要: Carbon-based materials were prepared to catalyze the V 3+/V 2+ couple of vanadium redox flow battery using chitosan as the preliminary material and FeCl 3 as activating agent. Graphite microcrystals were the main structures of the obtained catalyst (CTS-Fe-900) activated by FeCl 3, and they contained a large number of curled and overlapped carbon nanosheets. Compared with CTS-D-900 (without FeCl 3 as an activating agent), CTS-Fe-900 exhibits a better structure, higher graphitization degree, stronger current response, and …

参考文章(31)
Yanrong Lv, Lu Zhang, Gang Cheng, Pengfei Wang, Tianze Zhang, Chuanchang Li, Yingqiao Jiang, Zhangxing He, Lei Dai, Ling Wang, Preparation of Carbon Nanosheet by Molten Salt Route and Its Application in Catalyzing VO 2+ /VO 2 + Redox Reaction Journal of The Electrochemical Society. ,vol. 166, ,(2019) , 10.1149/2.0371906JES
J. Liu, Z.A. Wang, X.W. Wu, X.H. Yuan, J.P. Hu, Q.M. Zhou, Z.H. Liu, Y.P. Wu, Porous carbon derived from disposable shaddock peel as an excellent catalyst toward VO2+/VO2+ couple for vanadium redox battery Journal of Power Sources. ,vol. 299, pp. 301- 308 ,(2015) , 10.1016/J.JPOWSOUR.2015.09.004
Abdulmonem Fetyan, Igor Derr, Manoj Krishna Kayarkatte, Joachim Langner, Denis Bernsmeier, Ralph Kraehnert, Christina Roth, Electrospun Carbon Nanofibers as Alternative Electrode Materials for Vanadium Redox Flow Batteries ChemElectroChem. ,vol. 2, pp. 2055- 2060 ,(2015) , 10.1002/CELC.201500284
M. Skyllas-Kazacos, M. H. Chakrabarti, S. A. Hajimolana, F. S. Mjalli, M. Saleem, Progress in Flow Battery Research and Development Journal of The Electrochemical Society. ,vol. 158, ,(2011) , 10.1149/1.3599565
Piergiorgio Alotto, Massimo Guarnieri, Federico Moro, Redox flow batteries for the storage of renewable energy: A review Renewable & Sustainable Energy Reviews. ,vol. 29, pp. 325- 335 ,(2014) , 10.1016/J.RSER.2013.08.001
Tao Wu, Kelong Huang, Suqin Liu, Shuxin Zhuang, Dong Fang, Sha Li, Dan Lu, Anqun Su, Hydrothermal ammoniated treatment of PAN-graphite felt for vanadium redox flow battery Journal of Solid State Electrochemistry. ,vol. 16, pp. 579- 585 ,(2012) , 10.1007/S10008-011-1383-Y
Ki Jae Kim, Min-Sik Park, Jae-Hun Kim, Uk Hwang, Nam Jin Lee, Goojin Jeong, Young-Jun Kim, Novel catalytic effects of Mn3O4 for all vanadium redox flow batteries Chemical Communications. ,vol. 48, pp. 5455- 5457 ,(2012) , 10.1039/C2CC31433A