Fluorine-Ion-Mediated Electrodeposition of Rhombus-Like ZnFOH Nanorod Arrays: An Intermediate Route to Novel ZnO Nanoarchitectures

摘要: Novel rhombus-like ZnO nanorod (NR) arrays were achieved via a facile two-step synthesis strategy based on first low-temperature aqueous electrodeposition of vertically aligned rhombic ZnFOH NR in the presence fluoride and second pyrolysis intermediate into with same morphology. The fluorine-ion-mediated mechanism was confirmed for time, proposed formation process that NRs characterized by mesoporous structure derived from electrodeposited corroborated systematic structural characterization as-prepared products. A dye-sensitized solar cell (DSSC) larger surface roughness factor assembled, higher conversion efficiency 0.69% attained comparison to 0.47% DSSC hexagon-like absence fluoride. Further, we demonstrate unique also possessed capability constructing complex nanoarchitectures 1D as building blocks.