Some effects of intra-atomic electron correlation on XPS multiplet splittings
作者： P. Anthony Cox
DOI: 10.1016/0368-2048(81)85006-2
关键词: X-ray photoelectron spectroscopy 、 Valence electron 、 Condensed matter physics 、 Spin states 、 Large deviations theory 、 Atomic physics 、 Multiplet 、 Chemistry 、 Measure (mathematics) 、 Electronic correlation
摘要: Abstract Large deviations between experimental and theoretical values for XPS exchange splittings have been attributed to intra-atomic correlation effects. It is shown here how these can reduce by a factor which roughly independent of the valence electron configuration, spin state, or covalency. The use measure such effects may therefore be justified, in spite large contributions from correlation.
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