Preparation of sulfated zirconia catalysts with improved control of sulfur content, III. Effect of conditions of catalyst synthesis on physical properties and catalytic activity
作者： Dan Fărcaşiu , Jing Qi Li
DOI: 10.1016/S0926-860X(98)00197-5
关键词: Isomerization 、 Sulfation 、 Calcination 、 Methylcyclopentane 、 Cubic zirconia 、 Cyclohexane 、 Chemistry 、 Inorganic chemistry 、 Catalysis 、 Zirconium
摘要: Abstract In the preparation of sulfated zirconia catalysts (SZ) by controlled impregnation technique, properties products, including catalytic activity, are influenced precursor from which Zr(OH)4 is obtained, pH its precipitation, and temperature time calcination after sulfation. The best catalyst for isomerization methylcyclopentane (MCP) to cyclohexane was obtained zirconium oxynitrate as precursor, with precipitation conducted at a constant 7 in air, sulfation previously described, 610°C 5 h. nature chemical process occurring during discussed light results obtained.
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