Toughening mechanism of epoxy modified with CTBN elastomer adhesive j oints

作者: M. Ochi , K. Mimura , H. Motobe

DOI: 10.1163/156856194X01077

关键词: ToughnessPhase (matter)CavitationBond strengthElastomerShear (sheet metal)Composite materialEpoxyMaterials scienceAdhesiveMaterials ChemistryMechanics of MaterialsGeneral chemistrySurfaces, Coatings and FilmsSurfaces and Interfaces

摘要: The effect of modification with CTBN on the bonding properties an epoxy system cured 1-o-tolylbiguanide (TBG) was investigated and compared results ethylenediamine (EDA). TBG used as a model dicyandiamide, which is typical latent curing agent. bond strength toughness TBG-cured increased considerably addition modifier, whereas values for EDA-cured were not influenced by modification. In former system, cavitation CTBN-dispersed phase plastic deformation matrix observed in vicinity crack tip. These phenomena system. addition, crosslink density much lower than that Thus, it concluded high modified caused also shear yielding low-crosslinked matrix.

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