Unravelling the Redox‐catalytic Behavior of Ce4+ Metal–Organic Frameworks by X‐ray Absorption Spectroscopy
作者： Simon Smolders , Kirill A. Lomachenko , Bart Bueken , Arnaud Struyf , Aram L. Bugaev
关键词: Redox 、 Photochemistry 、 X-ray absorption spectroscopy 、 Catalysis 、 Benzyl alcohol 、 Catalytic cycle 、 Metal-organic framework 、 Alcohol oxidation 、 Absorption spectroscopy
摘要: … Here, we report an improved catalytic activity for the TEMPO-mediated aerobic oxidation of benzyl alcohol by replacing Ce-UiO-66 with Ce-MOF-808 ([Ce 6 O 4 (OH) 4 (btc) 2 (OH) 6 ]; …
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