作者: Omar A. Lafi , Mousa M.A. Imran
DOI: 10.1016/J.RADPHYSCHEM.2009.08.005
关键词: Gamma irradiation 、 Differential scanning calorimetry 、 Crystallization 、 Glass transition 、 Activation energy 、 Chalcogenide glass 、 Irradiation 、 Mineralogy 、 Analytical chemistry 、 Materials science 、 Thermal stability
摘要: Abstract Se 96 Sn 4 chalcogenide glass was prepared by melt quenching technique and exposed, at room temperature, to different doses of 4, 8, 12, 24 33 kGy high-energy 60 Co gamma irradiation. Differential scanning calorimeter (DSC) used under non-isothermal condition determine the transition temperature T g , onset c peak p temperatures crystallization, un-irradiated γ-irradiated samples, four heating rates. The variation with rates utilized calculate activation energy E t for glass, using methods suggested Kissinger Moynihan. Based on obtained values characteristic thermal stability monitored through calculation S parameter crystallization rate factor 〈 K 〉 irradiated glass. Results reveal that, as γ-dose increases up 12 kGy then decreases higher but remains more than that Meanwhile, both attain their minimum same dose is thermally stable this particular dose.