From molecular models to system analysis for lithium battery electrolytes
作者： John B Kerr , Steven E Sloop , Gao Liu , Yong Bong Han , Jun Hou
DOI: 10.1016/S0378-7753(02)00202-1
关键词: Electrode 、 Electrolyte 、 Ion 、 Chemical physics 、 Separator (electricity) 、 Lithium battery 、 Passivation 、 Inorganic chemistry 、 Rheology 、 Chemistry 、 Polymer
摘要: The behavior of polymer electrolytes in lithium batteries is reviewed in the context of molecular scale models as well as on the system scale. It is shown how the molecular structure of the electrolyte strongly influences ion transport through the polymer as well as across the interfaces and determines the values of a number of parameters needed for system models that can predict the performance of the battery (eg κ, D, t0+ and i0). The interaction of the electrolyte with the electrodes not only leads to transfer of the lithium ion …
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