A stable radical in the ribose moiety of X-irradiated 3'-cytidylic acid and its relation to a similar radical in cytidine: an ESR-ENDOR study.

作者: William A. Bernhard , Jürgen Hüttermann , Adolf Müller , David M. Close , George W. Fouse

DOI: 10.2307/3574322

关键词: Organic chemistryRiboseMoietyResonance (chemistry)Electron paramagnetic resonanceNucleotideMedicinal chemistryRadicalChemistryRadiation chemistryCytidine

摘要: A stable free radical, labeled 3αH, is formed in 3′-cytidylic acid (3′CMP) single crystals by X-irradiating at 77 K and then warming to above room temperature. It remains up 150°C. ESR an...

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