Investigation of Photoluminescence Properties for Dibenzosiloles and Tetrabenzospirosilole

作者: Seunghyun Jang

DOI: 10.13160/RICNS.2010.3.2.107

关键词: Host materialOptoelectronicsPhotoluminescenceSpectroscopyOLEDElectroactive materialsMaterials scienceDiodeConjugated systemElectron transport chain

摘要: Silicon-containing -conjugated compounds, especially silacyclopentadienes (siloles), have emerged as a new class of electroactive materials with good electron transport properties in OLEDs. 9,9'-spiro-9-silabifluorene compound well its starting material 2,2'-dibromobiphenyl been synthesized higher yields. Spirosilabifluorene is expected to be an efficient host for the blue-light emitting diodes. 9,9'-spiro-9-silabifluorene, 1,1-dichloro-1-silafluorene, and 1,1-dimethyl-1-silafluorene were characterized by -NMR, UV/Vis photoluminescence spectroscopy.

参考文章(12)
Takanobu Sanji, Takahiro Sakai, Chizuko Kabuto, Hideki Sakurai, Silole-Incorporated Polysilanes1a Journal of the American Chemical Society. ,vol. 120, pp. 4552- 4553 ,(1998) , 10.1021/JA973252H
Yoichi Yamaguchi, Design of novel σ*-π* conjugated polysilanes Synthetic Metals. ,vol. 82, pp. 149- 153 ,(1996) , 10.1016/S0379-6779(96)03782-4
Yuxia Liu, Thomas C. Stringfellow, David Ballweg, Ilia A. Guzei, Robert West, Structure and chemistry of 1-silafluorenyl dianion, its derivatives, and an organosilicon diradical dianion. Journal of the American Chemical Society. ,vol. 124, pp. 49- 57 ,(2002) , 10.1021/JA011821M
Honglae Sohn, Ryan R. Huddleston, Douglas R. Powell, Robert West, Kunio Oka, Xu Yonghua, An Electroluminescent Polysilole and Some Dichlorooligosiloles Journal of the American Chemical Society. ,vol. 121, pp. 2935- 2936 ,(1999) , 10.1021/JA983350I
Kohei Tamao, Manabu Uchida, Takenori Izumizawa, Kenji Furukawa, Shigehiro Yamaguchi, Silole Derivatives as Efficient Electron Transporting Materials Journal of the American Chemical Society. ,vol. 118, pp. 11974- 11975 ,(1996) , 10.1021/JA962829C
Xing-Hua Zhou, Ji-Chao Yan, Jian Pei, Synthesis and relationships between the structures and properties of monodisperse star-shaped oligofluorenes. Organic Letters. ,vol. 5, pp. 3543- 3546 ,(2003) , 10.1021/OL035461E
Khai Leok Chan, Mary J. McKiernan, Carl R. Towns, Andrew B. Holmes, Poly(2,7-dibenzosilole): A Blue Light Emitting Polymer Journal of the American Chemical Society. ,vol. 127, pp. 7662- 7663 ,(2005) , 10.1021/JA0508065
Yonghua Xu, Takahiro Fujino, Hiroyoshi Naito, Takaaki Dohmaru, Kunio Oka, Honglae Sohn, Robert West, Electroluminescent Properties of a Novel σ*–π* Conjugated Polymer, Poly[1,1-(2,3,4,5-tetraphenylsilole)] Japanese Journal of Applied Physics. ,vol. 38, pp. 6915- 6918 ,(1999) , 10.1143/JJAP.38.6915
Shigehiro Yamaguchi, Tomonori Endo, Manabu Uchida, Takenori Izumizawa, Kenji Furukawa, Kohei Tamao, Toward New Materials for Organic Electroluminescent Devices: Synthesis, Structures, and Properties of a Series of 2, 5-Diaryl-3,4-diphenylsiloles Chemistry: A European Journal. ,vol. 6, pp. 1683- 1692 ,(2000) , 10.1002/(SICI)1521-3765(20000502)6:9<1683::AID-CHEM1683>3.0.CO;2-M