Microwave-assisted magnesium phosphate coating on the AZ31 magnesium alloy

作者: Yufu Ren , Elham Babaie , Boren Lin , Sarit B Bhaduri

DOI: 10.1088/1748-605X/AA78C0

关键词: 5052 aluminium alloyChemical engineeringMagnesiumMagnesium alloyCorrosionMagnesium phosphateMaterials science6063 aluminium alloySimulated body fluidCoating

摘要: Due to the combination of many unique properties, magnesium alloys have been widely recognized as suitable metallic materials for fabricating degradable biomedical implants. However, extremely high degradation kinetics in physiological environment hindered their clinical applications. This paper reports first time use a novel microwave-assisted coating process deposit phosphate (MgP) coatings on Mg alloy AZ31 and improve its vitro corrosion resistance. Newberyite trimagnesium hydrate (TMP) layers with distinct features were fabricated at various processing times temperatures. Subsequently, resistance, behavior, bioactivity cytocompatibility MgP coated samples investigated. The potentiodynamic polarization tests reveal that current density simulated body fluid (SBF) is significantly suppressed by deposited coatings. Additionally, it seen remarkably reduced mass loss after immersion SBF two weeks promoted precipitation apatite particles. viability preosteoblast cells cultured extracts indicates can alloy. These attractive results suggest coatings, serving protective bioactive layer, enhance resistance biological response alloys.

参考文章(42)
Sergey V. Dorozhkin, Calcium orthophosphate coatings on magnesium and its biodegradable alloys Acta Biomaterialia. ,vol. 10, pp. 2919- 2934 ,(2014) , 10.1016/J.ACTBIO.2014.02.026
R. Zeng, W. Dietzel, F. Witte, N. Hort, C. Blawert, Progress and Challenge for Magnesium Alloys as Biomaterials Advanced Engineering Materials. ,vol. 10, ,(2008) , 10.1002/ADEM.200800035
Frank Witte, Norbert Hort, Carla Vogt, Smadar Cohen, Karl Ulrich Kainer, Regine Willumeit, Frank Feyerabend, Degradable biomaterials based on magnesium corrosion Current Opinion in Solid State & Materials Science. ,vol. 12, pp. 63- 72 ,(2008) , 10.1016/J.COSSMS.2009.04.001
S. Jalota, S. B. Bhaduri, A. C. Tas, Effect of carbonate content and buffer type on calcium phosphate formation in SBF solutions. Journal of Materials Science: Materials in Medicine. ,vol. 17, pp. 697- 707 ,(2006) , 10.1007/S10856-006-9680-1
Kjell Ove Kongshaug, Helmer Fjellvåg, Karl Petter Lillerud, The synthesis and crystal structure of a hydrated magnesium phosphate Mg3(PO4)2.4H2O Solid State Sciences. ,vol. 3, pp. 353- 359 ,(2001) , 10.1016/S1293-2558(00)01109-2
Yufu Ren, Huan Zhou, Maryam Nabiyouni, Sarit B. Bhaduri, Rapid coating of AZ31 magnesium alloy with calcium deficient hydroxyapatite using microwave energy Materials Science and Engineering: C. ,vol. 49, pp. 364- 372 ,(2015) , 10.1016/J.MSEC.2015.01.046
Frank Witte, The history of biodegradable magnesium implants: a review. Acta Biomaterialia. ,vol. 6, pp. 1680- 1692 ,(2010) , 10.1016/J.ACTBIO.2010.02.028
Jing-xin Yang, Yan-peng Jiao, Qing-shui Yin, Yu Zhang, Tao Zhang, Calcium phosphate coating on magnesium alloy by biomimetic method: Investigation of morphology, composition and formation process Frontiers of Materials Science in China. ,vol. 2, pp. 149- 155 ,(2008) , 10.1007/S11706-008-0025-5
R. Boistelle, F. Abbona, Morphology, habit and growth pf newberyite crystals (MgHPO4·3 H2O) Journal of Crystal Growth. ,vol. 54, pp. 275- 295 ,(1981) , 10.1016/0022-0248(81)90472-3