Contribution to the theory of the retention index system : IV. Retention index and molecular structure. Calculation of retention indices of olefins, cyclic hydrocarbons and homologues of benzene hydrocarbons on the basis of their molecular structures

作者: J. Takács , Zs. Tálas , I. Bernáth , Gv. Czakó , A. Fischer

DOI: 10.1016/S0021-9673(01)91222-1

关键词: MoleculeBenzeneKovats retention indexCyclic HydrocarbonsSqualaneAdditive functionStationary phaseChemistryChromatographyBasis (linear algebra)

摘要: Abstract In a previous paper, the fundamentals of relation between retention index and molecular structure were derived, additivity indices was shown with help gas chromatographic literature. this same problem is discussed on squalane as stationary phase for olefins, cyclic hydrocarbons homologues benzene. Our investigations also extended theoretical aspects problem, especially at interaction connections.

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