Crystal structure refinements of synthetic chalcocyanite (CUSO4) and zincosite (ZnSO4)
作者： M. Wildner , G. Giester
DOI: 10.1007/BF01163035
关键词: Inorganic chemistry 、 Single crystal 、 Crystal structure 、 Crystallography 、 Cell parameter 、 Inorganic compound 、 Group (periodic table) 、 Space (mathematics) 、 Chemistry 、 X-ray crystallography
摘要: The crystal structures of synthetic CuSO4 and ZnSO4 were refined to R=0.048, 0.037 (Rw = 0.039, 0.035) using single X-ray data up sinθ/λ 0.8 A−1. Space group Prima, cell parameters: a=8.409(1), 8.604 (5) A; b=6.709(1), 6.746 c=4.833 (1), 4.774 (3) Z =4. refinements essentially confirmed the atomic arrangements earlier works, but parameters could be determined with considerably higher accuracy.
springer.com
harvard.edu
sci-hub.se 参考文章(24)
James A. Ibers, Lonsdale, Kathleen, Dame, John S. Kasper, Gerard D. Rieck, Walter C. Hamilton, Norman Fordyce McKerron Henry, Caroline H. MacGillavry, International tables for X-ray crystallography UT Back-in-Print Service. ,(1962)
Howard E. Swanson, Eleanor Tatge, Ruth K. Fuyat, Standard X‐Ray Diffraction Powder Patterns Physics Today. ,vol. 7, pp. 22- 22 ,(1954) , 10.1063/1.3061729
I. Almodovar, B. C. Frazer, J. J. Hurst, D. E. Cox, P. J. Brown, Magnetic Structure of Cu So 4 Physical Review. ,vol. 138, pp. 153- 155 ,(1965) , 10.1103/PHYSREV.138.A153
H. Fuess, G. Will, Bestimmung der Kristallstruktur der Selenate MSeO4 (MMn, Co, Ni) durch Röntgen‐ und Neutronenbeugung Zeitschrift für anorganische und allgemeine Chemie. ,vol. 358, pp. 125- 137 ,(1968) , 10.1002/ZAAC.19683580304
R. J. Poljak, On the structure of anhydrous nickel sulfate Acta Crystallographica. ,vol. 11, pp. 306- 306 ,(1958) , 10.1107/S0365110X58000797
Hendrik C. Snyman, Carl W. F. T. Pistorius, Crystallographic Data for NiSeO4 and its Hydrates Zeitschrift für anorganische und allgemeine Chemie. ,vol. 324, pp. 157- 161 ,(1963) , 10.1002/ZAAC.19633240305
C. W. F. T. Pistorius, Lattice constants and space groups of the low and high temperature polymorphic forms of anhydrous cobaltous sulfate Acta Crystallographica. ,vol. 14, pp. 543- 544 ,(1961) , 10.1107/S0365110X61001716
J. D. Dunitz, P. Pauling, Polymorphism in anhydrous cobalt sulphate Acta Crystallographica. ,vol. 18, pp. 737- 740 ,(1965) , 10.1107/S0365110X65001688
Carl W. F. T. Pistorius, Polymorphism in the anhydrous sulphates of Mn, Fe, Co, Ni, Cu and Zn to 140,000 bars and 750°C Zeitschrift Fur Kristallographie. ,vol. 116, pp. 220- 250 ,(1961) , 10.1524/ZKRI.1961.116.3-6.220
I. D. Brown, K. K. Wu, Empirical parameters for calculating cation–oxygen bond valences Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. ,vol. 32, pp. 1957- 1959 ,(1976) , 10.1107/S0567740876006869