Chemical bonding theory of single crystal growth and its application to ϕ 3′′ YAG bulk crystal

作者: Congting Sun , Dongfeng Xue

DOI: 10.1039/C3CE42292E

关键词: Crystal structureCrystalMaterials scienceKinetic energyMolecular physicsChemical bondNucleationAnisotropyCrystallographySingle crystalSapphire

摘要: The growth of YAG bulk crystals was studied using both theoretical calculations based on the anisotropic chemical bonding conditions and practical via Czochralski (Cz) method. theory single crystal quantitatively describes behaviors constituent atoms during crystallizing, which can be applied to thermodynamic crystals. Both symmetry determine projection configuration along pulling direction ridges in shoulder grown [111] direction. During Cz process crystals, relative low rate directions results exposure surfaces normal directions. However, energy density at intersection two adjacent is higher, leading truncated-hexagon ϕ 3′′ successfully grown. Our present work provides a promising approach achieve controllable for functional kinetic controls.

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