Dendrimers and methods of preparing same through proportionate branching

作者: Xuyi Yue , Yihua (Bruce) Yu

DOI:

关键词: Branching (polymer chemistry)Chemical physicsPolymer chemistryDendrimerChemistry

摘要: The present invention provides for monodispersed dendrimers having a core, branches and periphery ends, wherein the number of increases exponentially from core to end length thereby providing attachment chemical species at ends without exhibiting steric hindrance.

参考文章(25)
V. Percec, C.-H. Ahn, G. Ungar, D. J. P. Yeardley, M. Möller, S. S. Sheiko, Controlling polymer shape through the self-assembly of dendritic side-groups Nature. ,vol. 391, pp. 161- 164 ,(1998) , 10.1038/34384
AI Cooper, JD Londono, G Wignall, JB McClain, ET Samulski, JS Lin, A Dobrynin, M Rubinstein, ALC Burke, JMJ Frechet, JM DeSimone, Extraction of a hydrophilic compound from water into liquid CO2 using dendritic surfactants Nature. ,vol. 389, pp. 368- 371 ,(1997) , 10.1038/38706
V. Percec, M. Glodde, T. K. Bera, Y. Miura, I. Shiyanovskaya, K. D. Singer, V. S. K. Balagurusamy, P. A. Heiney, I. Schnell, A. Rapp, H.-W. Spiess, S. D. Hudson, H. Duan, Self-organization of supramolecular helical dendrimers into complex electronic materials Nature. ,vol. 419, pp. 384- 387 ,(2002) , 10.1038/NATURE01072
George R. Newkome, Carol Shreiner, Dendrimers derived from 1 → 3 branching motifs. Chemical Reviews. ,vol. 110, pp. 6338- 6442 ,(2010) , 10.1021/CR900341M
D. I. Svergun, Determination of the regularization parameter in indirect-transform methods using perceptual criteria Journal of Applied Crystallography. ,vol. 25, pp. 495- 503 ,(1992) , 10.1107/S0021889892001663
Petr V. Konarev, Vladimir V. Volkov, Anna V. Sokolova, Michel H. J. Koch, Dmitri I. Svergun, PRIMUS: a Windows PC-based system for small-angle scattering data analysis Journal of Applied Crystallography. ,vol. 36, pp. 1277- 1282 ,(2003) , 10.1107/S0021889803012779
Dénes Szabó, János Mohl, Ana-Maria Bálint, Andrea Bodor, József Rábai, Novel generation ponytails in fluorous chemistry: Syntheses of primary, secondary, and tertiary (nonafluoro-tert-butyloxy)ethyl amines Journal of Fluorine Chemistry. ,vol. 127, pp. 1496- 1504 ,(2006) , 10.1016/J.JFLUCHEM.2006.06.020
S SVENSON, D TOMALIA, Dendrimers in biomedical applications--reflections on the field. Advanced Drug Delivery Reviews. ,vol. 57, pp. 2106- 2129 ,(2005) , 10.1016/J.ADDR.2005.09.018
Zhong-Xing Jiang, Yihua Bruce Yu, Fluorous mixture synthesis of asymmetric dendrimers. Journal of Organic Chemistry. ,vol. 75, pp. 2044- 2049 ,(2010) , 10.1021/JO100102A